Papers

  1. Palladium-catalyzed cycloisomerization of thiocarbamates with consecutive formation of quaternary carbon and sulfide
    Kumazawa, H.; Nakada, M. Tetrahedron Lett. 2025, 154, 155384
    DOI: 10.1016/j.tetlet.2024.155384
  2. Synthetic studies on fusicoccin A: Enantioselective synthesis of the C-ring fragment
    Hayashi, K.; Nakada, M. Tetrahedron Lett. 2024, 153, 155364
    DOI: 10.1016/j.tetlet.2024.155364
  3. Palladium-Catalyzed Cycloisomerization of Carbamimidothioates
    Kumazawa, H.; Mizoguchi, K.; Okura, Y.; Nakada, M. Synlett 2024, 35, 1817-1821.
    DOI: 10.1055/s-0043-1763663
  4. Palladium-Catalyzed Carbothiolation Using Thioesters with Forming a Quaternary Carbon
    Okura, Y.; Ito, R.; Kumazawa, H.; Nakada, M. Synlett 2024, 35, 1788-1794.
    DOI: 10.1055/a-2248-3205
  5. Pd-Catalyzed Stereoselective Construction of Benzo-Fused Decalines with a Quaternary Carbon
    Setsumasa, H.; Imai, K.; Kobayashi, I.; Nakada, M. Org. Lett. 2023, 25, 7953-7957.
    DOI: 10.1021/acs.orglett.3c02233
  6. Pd-Catalyzed Intramolecular Cyclization–Thiocarbonylation Cascade Using Thioesters
    Ito, R.; Okura, Y.; Nakada, M. Synlett 2023, 34, 2319-2322.
    DOI: 10.1055/s-0042-1751490
  7. Enantioselective Formal Total Synthesis of Damsin
    Sugiyama, R.; Nakada, M. Synlett 2023, 34, 1029-1032.
    DOI: 10.1055/a-2017-3636
  8. Preparation of New Chiral Building Blocks by a Mukaiyama–Michael Reaction
    of 2-(Phenylsulfonyl)cyclopent-2-en-1-one
    Sugiyama, R.; Nakada, M. Synlett 2023, 34, 1235-1240.
    DOI: 10.1055/a-2030-7082
  9. Research on the Efficient Enantioselective Total Synthesis of Useful Bioactive Polycyclic Compounds
    Nakada, M. Bull. Chem. Soc. Jpn. 2022, 95, 1117-1147.
    DOI: 10.1246/bcsj.20210329
  10. Construction of Successive Stereogenic Centers of ent-Kauranoid through an Oxidative Dearomatization/1,2-Shift Cascade
    Imamura, Y.; Mizutani, H.; Nakada, M. Synlett 2022, 33, 1556-1562.
    DOI: 10.1055/a-1855-3777
  11. Palladium-Catalyzed Thiocarbonylations with Triisopropylsilyl Thioethers
    Hosoya, Y.; Mizoguchi, K.; Yasukochi, H.; Nakada, M. Synlett 2022, 33, 495-501.
    DOI: 10.1055/a-1733-6073
  12. Preparation of 2,3-Dihydrobenzo[b]thiophene Bearing Benzylic Quaternary Carbon by Palladium-Catalyzed Cascade Reaction
    Hosoya, Y.; Yasukochi, H.; Mizoguchi, K.; Nakada, M. Heterocycles 2022, 104, 12, 655-666.
    DOI: 10.3987/COM-21-14611
  13. Enantioselective Total Synthesis of Cotylenin A
    Uwamori, M.; Osada, R.; Sugiyama, R.; Nagatani, K.; Nakada, M. J. Am. Chem. Soc. 2020, 142, 5556-5561.
    Synfacts, 2020, 16, 0623.
    DOI: 10.1021/jacs.0c01774
  14. Synthetic Studies on Keramaphidin B: Formation of a Macrocyclic Ring by Intramolecular Diels-Alder Reaction
    Shimoda, H.; Shibata, T.; Sekine, D.; Nakada, M. Heterocycles 2020, 100, 1, 3-11.
    DOI: 10.3987/COM-19-14117
  15. Palladium-catalyzed carbothiolation via trapping of the σ-alkyl palladium intermediate with RSTIPS
    Hosoya, Y.; Kobayashi, I.; Mizoguchi, K.; Nakada, M. Org. Lett. 2019, 21, 8280-8284.
    DOI: 10.1021/acs.orglett.9b03046
  16. Preparation of a Chiral Building Block by an Organocatalytic Asymmetric Intramolecular Michael Reaction
    Sato, Y.; Hosoya, Y.; Kobayashi, I.; Adachi, K.; Nakada, M. Asian J. Org. Chem. 2019, 8, 1033-1036.
    DOI: 10.1002/ajoc.201900178
  17. Research on unique masked ortho-​benzoquinone, monohemiaminal: synthesis and reactions
    Matsumoto, Y.; Nakamura, A.; Saito, E.;Nakada, M. Heterocycles 2018, 97, 232-252.
    DOI: 10.3987/COM-17-S(T)11
  18. Efficient Preparation of Cyclic α-​Alkylidene β-​Oxo Imides by Using a Flow Microreactor System
    Komuro, K.; Nagaki, A.; Shimoda, H.; Uwamori, M.; Yoshida, J.; Nakada, M. Synlett 2018, 29 1989-1994.
    DOI: 10.1055/s-0037-1610228
  19. Formal total synthesis of (-)-taxol
    Utsugi, M.; Iwamoto, M.; Hirai, S.; Kawada, H.; Nakada, M. Yuki Gosei Kagaku Kyokaishi 2017, 75, 1102-1115.
    DOI: 10.5059/yukigoseikyokaishi.75.1102
  20. Research on Liebeskind-Srogl coupling/intramoleular Diels-Alder reaction cascade
    Fujii, T.; Oki, Y.; Nakada, M. Tetrahedron Lett. 2018, 59, 882-886.
    DOI: 10.1016/j.tetlet.2018.01.046
  21. Substituenet effect on the reaction pathway of Au(I)-catalyzed ene-yne cycloisomerization
    Oki, Y.; Nakada, M. Tetrahedron Lett. 2018, 59, 922-925.
    DOI: 10.1016/j.tetlet.2018.01.068
  22. Research on Au(I)-catalyzed ene-yne cycloisomerization for construction of quassinoid scaffold
    Oki, Y.; Nakada, M. Tetrahedron Lett. 2018, 59, 926-929.
    DOI: 10.1016/j.tetlet.2018.01.069
  23. Synthesis and reaction of othro-benzoquinone monohemiaminals
    Saito E.; Matsumoto Y.; Nakamura A, Namera, Y.; Nakada, M. Org. Lett. 2018, 20, 692-695.
    DOI: 10.1021/acs.orglett.7b03824
  24. Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate
    Inoue, S.; Nagatani, K.; Hoshino, Y.; Tezuka H.; Nakada, M. Heterocycles 2017, 94, 541-553.
    DOI: 10.3987/com-17-13656
  25. Enantio- and Stereoselective Construction of Atisane Scaffold via Organocatalytic Intramolecular Michael Reaction and Diels−Alder Reaction
    Sekita, H.; Adachi, K.; Kobayashi, I.; Sato, Y.; Nakada, M. Org. Lett. 2017, 19, 2390-2393.
    DOI: 10.1021/acs.orglett.7b00918
  26. Enantioselective preparation of C-ring fragment of cotylenin A via catalytic asymmetric intramolecular cyclopropanation of α-diazo β-keto ester
    Nagatani, K.; Hoshino, Y.; Tezuka, H.; Nakada, M. Tetrahedron Lett. 2017, 58, 959-962.
    DOI: 10.1016/j.tetlet.2017.01.076
  27. Enantioselective Mukaiyama-Michael Reaction of Cyclic α-Alkylidene β-Keto Phosphine Oxide and Phosphonate and Asymmetric Synthesis of (R)-Homosarkomycin
    Nagatani, K.; Minami, A.; Tezuka, H.; Hoshino, Y.; Nakada, M. Org. Lett. 2017, 19, 810-813.
    DOI: 10.1021/acs.orglett.6b03798
  28. Catalytic Asymmetric Intramolecular Cyclopropanation of α-Diazo-α-Silyl Acetate
    Inoue, S.; Nagatani, K.; Tezuka, H.; Hoshino, Y.; Nakada, M. Synlett 2017, 28, 1065-1070.
    DOI: 10.1055/s-0036-1588414
  29. Research on the design, synthesis, and catalytic activity of chiral N-heterocyclic carbene ligand-metal complexes
    Usui, K.; Yoshida, T.; Nakada, M. Tetrahedron: Asymmetry 2016, 27, 107-113.
    DOI: 10.1016/j.tetasy.2015.12.006
  30. Synthesis of a new chiral C2-symmetric NHC-AuCl complex
    Okitsu, N.; Yoshida, T.; Usui, K.; Nakada, M. Heterocycles 2016, 92, 720–732.
    DOI: 10.3987/COM-16-13408
  31. A Highly Stereoselective Intramolecular Diels-Alder Reaction for Construction of the AB-Ring Moiety of Bruceantin
    Usui, K.; Suzuki, T.; Nakada, M. Tetrahedron Lett. 2015, 56, 1247–1251.
    DOI: 10.1016/j.tetlet.2015.01.139
  32. Highly Enantioselective Catalytic Asymmetric Mukaiyama–Michael Reactions of Cyclic α-Alkylidene β-Oxo Imides
    Oyama, H.; Orimoto, K.; Niwa, T.; Nakada, M. Tetrahedron: Asymmetry 2015, 26, 262–270.
    DOI: 10.1016/j.tetasy.2015.01.012
  33. Enantioselective Total Synthesis of (+)-Bucidarasins A and C
    Usui, K.; Nakada, M. Heterocycles 2015, 91, 332-350.
    DOI: 10.3987/COM-14-13161
  34. Synthesis and Characterizatoin of A New C2-Symmetrical Chiral Tridentate N-Heterocyclic Carbene Ligand Coordinated Cr(III) Complex
    Uetake, Y.; Niwa, T.; Nakada, M. Tetrahedron: Asymmetry 2015, 26, 158-162.
    DOI: 10.1016/j.tetasy.2015.01.003
  35. Highly Enantioselective Catalytic Friedel–Crafts Reactions of Cyclic α-Alkylidene β-Oxo Imides
    Oyama, H.; Nakada, M. Tetrahedron: Asymmetry 2015, 26, 195-202.
    DOI: 10.1016/j.tetasy.2015.01.004
  36. Enantioselective Approach to Polycyclic Polyprenylated Acylphloroglucinols via Catalytic Asymmetric Intramolecular Cyclopropanation
    Uetake, Y.; Uwamori, M.; Nakada, M. J. Org. Chem. 2015, 80, 1735-1745.
    DOI: 10.1021/jo5026699.
  37. Highly Enantioselective Catalytic Asymmetric [2+2] Cycloadditions of Cyclic α-Alkylidene β-Oxo Imides with Ynamides
    Enomoto, K.; Oyama, H.; Nakada, M. Chem. -Eur. J. 2015, 21, 2798-2802.
    DOI: 10.1002/chem.201406189.
  38. A concise approach to tetracyclic spiroamine scaffold of erythrinane alkaloids via an oxidative dearomatization-spirocyclization sequence
    Saito, E.; Nakamura E.; Heterocycles (prof. Kuwajima Special issue) 2015, 90, 1387-1395.
    DOI: 10.3987/COM-14-S(K)95.
  39. Formal Total Synthesis of (−)-Taxol through Pd-Catalyzed Eight-Membered Carbocyclic Ring Formation
    Hirai, S.; Utsugi, M.; Iwamoto, M.; Nakada, M. Chem.–Eur. J. 2015, 21, 355-359.
    *Selected as a Hot Paper.
    DOI: 10.1002/chem.201404295
  40. Synthesis of Cycloalkanone-Fused Cyclopropanes by Au(I)-Catalyzed Oxidative Ene-Yne Cyclizations
    Uetake, Y.; Niwa, T.; Nakada, M. Tetrahedron Lett. 2014, 55, 6847-6850.
    DOI: 10.1016/j.tetlet.2014.10.084
  41. Total Synthesis of (−)-Bucidarasin A Starting from an Original Chiral Building Block
    Usui, K.; Kanbe, M.; Nakada, M. Org. Lett. 2014, 16, 4734-4737.
    DOI: 10.1021/ol502129u
  42. Enantioselective Total Syntheses of Cyathane Diterpenoids
    Nakada, M. Chem. Rec. 2014, 14, 641-662.
    DOI: 10.1002/tcr.201402019
  43. Enantioselective Total Synthesis of (–)-Cyathin B2
    Kobayakawa, Y.; Nakada, M. J. Antibiot. 2014, 67, 483-485.
    DOI: 10.1038/ja.2014.23
  44. Preparation of Chiral Building Blocks for the Enantioselective Total Synthesis of ent-Kauranoids by the Pig Liver Esterase-Catalyzed Asymmetric Hydrolysis of Dialkyl Malonate-Type Prochiral Diester
    Namiki, Y.; Fujii, T.; Nakada, M. Tetrahedron: Asymmetry 2014, 25, 718-724.
    DOI: 10.1016/j.tetasy.2014.01.019
  45. Direct Reductive Amination using Triethylsilane and Catalytic Bismuth(III) Chloride
    Matsumura, T.; Nakada, M. Tetrahedron Lett. 2014, 55, 1829-1834.
    DOI: 10.1016/j.tetlet.2014.01.132
  46. Enantioselective Total Synthesis of (–)-Scabronine D
    Kobayakawa, Y.; Nakada, M. Heterocycles 2014, 88, 669-677.
    DOI: 10.3987/COM-13-12921
  47. Stereoselective Construction of the ABC-Ring System of Fusidane Triterpenes via Intermolecular/Transannular Michael Reaction Cascade
    Fujii, T.; Nakada, M. Tetrahedron Lett. 2014, 55, 1597-1601.
    DOI: 10.1016/j.tetlet.2014.01.071
  48. Preparation of Imidazolinium Salts by the Pd-Catalyzed Reduction of Thioureas with Triethylsilane and Trialkylsilyl Triflate
    Matsumura, T.; Nakada, M. Tetrahedron Lett. 2014, 55, 1412-1415.
    DOI: 10.1016/j.tetlet.2014.01.022
  49. Highly Stereoselective Michael Reduction/Intramolecular Michael Reaction Cascade to Synthesize trans-Stereodiad Comprising an All-Carbon Quaternary Stereogenic center
    Fujii, T.; Orimoto, K.; Nakada, M. Tetrahedron Lett., 2014, 55, 1100-1103.
    DOI: 10.1016/j.tetlet.2013.12.110
  50. Facile Formation of Imidazolinium Salt by Reaction of Corresponding Diamine and Trimethyl Orthoformate in 1,1,1,3,3,3-Hexafluoroisopropanol
    Usui, K.; Nakada, M. Heterocycles, 2014, 88, 1539-1551.
    DOI: 10.3987/COM-13-S(S)80
  51. Enantioselective Total Syntheses of (–)-Scabronines G and A, and (–)-Episcabronine A
    Kobayakawa, Y.; Nakada, M. Angew. Chem., Int. Ed., 2013, 52, 7569-7573.
    Synfacts, 2013, 919.
    *The most-accessed article from Angew. Chem., Int. Ed. for June 2013.
    DOI: 10.1002/anie.201303224
  52. Allylic Oxidations in Natural Product Synthesis
    Nakamura, A.; Nakada, M. Synthesis 2013, 1421-1451.
    The most popular article of Synthesis in May-October 2013.
    DOI: 10.1055/s-0033-1338426
  53. Collective Total Synthesis of PPAPs: Total Synthesis of Clusianone via Intramolecular Cyclopropanation
    Uwamori, M.; Nakada, M. Nat. Prod. Commun. 2013, 8, 955-959.
    DOI: 10.1177/1934578X1300800721
  54. Enantioselective Total Synthesis of (+)-Colletoic Acid via Catalytic Asymmetric Intramolecular Cyclopropanation of an α–Diazo–β–Keto Diphenylphosphine Oxide
    Sawada, T.; Nakada, M. Org. Lett. 2013, 15, 1004–1007.
    DOI: 10.1021/ol303459x
  55. Stereoselective Total Synthesis of (±)-Hyperforin
    Uwamori, M.; Nakada, M. Tetrahedron. Lett. 2013, 54, 2022-2025.
    DOI: 10.1016/j.tetlet.2013.02.021
  56. Preparation of Imides via the Palladium-Catalyzed Coupling Reaction of Organostannanes with Methyl N-[Methoxy(methylthio)methylene]carbamate
    Orimoto, K.; Tomizawa, T. Oyama, H.; Namera, Y.; Niwa, T.; Nakada, M. Heterocycles 2013, 87, 827-840.
    DOI: 10.3987/COM-13-12662
  57. Research on the Pig Liver Esterase (PLE)-Catalyzed Kinetic Resolution of Half-Esters Derived from Prochiral Diesters
    Noguchi, N.; Tsuna, K.; Nakada, M. Tetrahedron: Asymmetry 2013, 24, 357–361.
    DOI: 10.1016/j.tetasy.2013.01.019
  58. Enantioselective Total Synthesis of (+)-Ophiobolin A
    Tsuna, K.; Noguchi, N.; Nakada, M. Chem.–Eur. J. 2013, 19, 5476-5486.
    DOI: 10.1002/chem.201204119
  59. A Short and Enantioselective Preparation of Taxol A-Ring Fragment
    Hirai, S.; Urushizako, N.; Miyano, M.; Fujii, T.; Nakada, M. Tetrahedron Lett. 2013, 54, 1888–1892.
    DOI: 10.1016/j.tetlet.2013.01.115
  60. Stereoselective Total Synthesis of Garsubellin A
    Uwamori, M.; Nakada, M. J. Antibiot. 2013, 66, 141–145.
    DOI: 10.1038/ja.2012.125
  61. Catalytic Asymmetric [4+2] Cycloadditions and Hosomi-Sakurai Reactions of α-Alkylidene β-Keto Imides
    Orimoto, K.; Oyama, H.; Namera, Y.; Niwa, T.; Nakada, M. Org. Lett. 2013, 15, 768–771.
    DOI: 10.1021/ol303381c
  62. Preparation of Imides via the Palladium-Catalyzed Coupling Reaction of Organoborons with Methyl N-[Methoxy(methylthio)methylene]carbamate as a One-Carbon Elongation Reaction
    Tomizawa, T.; Orimoto, K.; Oyama, H.; Namera, Y.; Niwa, T.; Nakada, M. Org. Lett. 2012, 14, 6294–6297.
    DOI: 10.1021/ol303062a
  63. A non-hem iron (III) complex having porphyrin-like properties that catalyzes asymmetric epoxidation
    Niwa, T.; Nakada, M. J. Am. Chem. Soc. 2012, 134, 13538–13541.
    Synfacts, 2012, 1219–1219.
    *The most read from Journal of the American Chemical Society in August 2012.
    DOI: 10.1021/ja304219s
  64. Pd-Catalyzed Reductive Cleavage of Alkyl Aryl Sulfides with Triethylsilane that is Accelerated by Trialkylsilylchloride
    Matsumura, T.; Niwa, T.; Nakada, M. Tetrahedron Lett. 2012, 53, 4313–4316.
    DOI: 10.1016/j.tetlet.2012.06.002
  65. Stereoselective Total Synthesis of Nemorosone
    Uwamori, M.; Saito, A.; Nakada, M. J. Org. Chem., 2012, 77, 5098-5107.
    *The most read from The Journal of Organic Chemistry (JOC) between April and June 2012.
    DOI: 10.1021/jo300646j
  66. Asymmetric and Highly Stereoselective Synthesis of the DEF-Ring Moiety of (-)-FR182877 and its Derivative Inducing Mitotic Arrest
    Kobayakawa, Y; Mori, Y.; Okajima, H.; Terada, Y.; Nakada, M. Org. Lett., 2012, 14, 2086-2089.
    DOI: 10.1021/ol300615w
  67. Preparation of New Chiral Bisoxazoline Ligands for the Catalytic Asymmetric Intramolecular Cyclopropanation of α-Diazo-β-Keto Phenyl Sulfone Affording a Useful Bicyclo[3.1.0]hexane Derivative
    Sawada, T.; Nakada, M. Tetrahedron: Asymmetry, 2012, 23, 350-356.
    DOI: 10.1016/j.tetasy.2012.02.021
  68. Synthetic Studies on (+)-Bucidarasin C: Two Diastereoselective Transannular Reactions Producing cis-Decaline Derivatives that Show Reversal Selectivity
    Nakahara, A.; Kanbe, M. Nakada, M. Tetrahedron Lett., 2012, 53, 1518-1522.
    DOI: 10.1016/j.tetlet.2012.01.058
  69. Synthesis of Medium-Sized Carbocyclic Ketones via the Intramolecular B-Alkyl Liebeskind-Srogl Coupling Reaction
    Tsuna, K.; Noguchi, N. Nakada, M. Tetrahedron Lett., 2011, 52, 7202-7205.
    DOI: 10.1016/j.tetlet.2011.10.148
  70. Convergent Total Synthesis of (+)-Ophiobolin
    Tsuna, K.; Noguchi, N. Nakada, M. Angew. Chem., Int. Ed., 2011, 50, 9452–9455.
    Synfacts, 2011, 1265–1265.
    *The most-accessed article from Angew. Chem., Int. Ed. for September 2011.
    DOI: 10.1002/anie.201104447
     ●タキソールの収束的不斉全合成への挑戦
    中田　雅久、平井　祥　化学工業, 2011, 62(6), 29-34.
  71. Enantioselective Divergent Approaches to both (-)-Platensimycin and (-)-Platencin
    Hirai, S.; Nakada, M. Tetrahedron, 2011, 67, 518–530.
    DOI: 10.1016/j.tet.2010.10.076
  72. An Enantioselective Approach to (-)-Platencin via Catalytic Asymmetric Intramolecular Cyclopropanation
    Hirai, S.; Nakada, M. Tetrahedron Lett., 2010, 51, 5076–5079.
    DOI: 10.1016/j.tetlet.2010.07.088
  73. Synthesis of NH006—A Photostable Fungicide Effective against Botrytis Cinerea—According to the Asymmetric Total Synthesis of MK8383
    Hayashi, N.; Yamamoto, K.; Minowa, N.; Nakada, M. Org. Biomol. Chem., 2010, 8, 1821-1825.
    DOI: 10.1039/B924096A
  74. Synthetic Studies on Nemorosone via Enantioselective Intramolecular Cyclopropanation
    Abe, M.; Saito, A.; Nakada, M. Tetrahedron Lett., 2010, 51, 1298-1302.
    DOI: 10.1016/j.tetlet.2009.12.147
  75. Structure Elucidation and Enantioselective Total Synthesis of the HMG-CoA Reductase Inhibitors, FR901512 and FR901516
    Inoue, M.; Nakada, M. Synthesis(Feature Article), 2009, 3694–3707.
    DOI: 10.1055/s-0029-1216980
  76. Asymmetric Total Synthesis of (+)-Carneic Acid A and Structure Revision of its Natural Form
    Yamakoshi, S.; Hayashi, N.; Suzuki, T.; Nakada, M. Tetrahedron Lett. 2009, 50, 5372–5375.
    DOI: 10.1016/j.tetlet.2009.07.024
     ●抗腫瘍性化合物FR182877の不斉全合成
    中田　雅久　ファルマシア, 2009, 45, 451-456.
    ●野崎‐檜山‐岸（NHK）反応有機クロム化合物の調製と反応
    中田　雅久　化学と教育, 2009, 57, 410-411.
  77. Development of Catalytic Asymmetric Intramolecular Cyclopropanation for α-Diazo-β-keto Sulfones and Applications to Natural Product Synthesis
    Honma, M.; Takeda, H.; Takano, M.; Nakada, M. Synlett (Accounts) 2009, 1695-1712.
    DOI: 10.1055/s-0029-1217363
  78. Total Synthesis of (–)-FR182877 through the Tandem IMDA-IMHDA Reaction and the Stereoselective Transition Metal-Mediated Transformations
    Tanaka, N.; Suzuki, T.; Matsumura, T.; Hosaya, Y.; Nakada, M. Angew. Chem., Int. Ed. 2009, 48, 2580-2583.
    Synfacts, 2009, 942–942.
    DOI: 10.1002/anie.200900097
  79. Alternative Synthetic Approach for (+)-Phomopsidin via the Highly Stereoselective TADA Reaction
    Hayashi, N.; Suzuki, T.; Usui, K.; Nakada, M. Tetrahedron 2009, 64, 888-895.
    DOI: 10.1016/j.tet.2008.11.030
  80. Asymmetric Total Synthesis of MK8383: The Iron-mediated Coupling Reaction is the Only Effective Method for the Construction of the (Z)-Trisubstituted Side-chain Alkene
    Hayashi, N.; Nakada, M. TetrahedronLett. 2009, 50, 232-235.
    DOI: 10.1016/j.tetlet.2008.10.138
     ●プラテンシマイシンは人類の救世主となるか？
    中田　雅久　化学, 2008, 63, 68-69.
  81. Preparation of a Chiral Building Block with a Stereogenic Benzylic Quaternary Carbon Center and Formal Total Synthesis of (-)-Physostigmine
    Asakawa, K.; Noguchi, N.; Takashima, S.; Nakada, M. Tetrahedron:Asymmetry, 2008, 19, 2304-2309.
    DOI: 10.1016/j.tetasy.2008.09.021
  82. Total Synthesis of (+)-Allocyathin B2, (-)-Erinacine B, and (-)-Erinacine E
    Watanabe, H.; Takano, M.; Nakada, M. J. Synth. Org.Chem. 2008, 66, 1116-1125.
    DOI: 10.1016/j.tetasy.2008.09.02110.5059/yukigoseikyokaishi.66.1116
  83. Synthetic Studies on the Taxane Skeleton: Effective Construction of the Eight-membered Carbocyclic Ring by Palladium-catalyzed Intramolecular α-Alkenylation of Methyl Ketone
    Utsugi, M.; Kamada, Y.; Miyamoto, H.; Nakada, M. Tetrahedron Lett. 2008, 49, 4754-4757.
    DOI: 10.1016/j.tetlet.2008.05.105
  84. Formal Total Synthesis of (-)-Physostigmine
    Asakawa, K.; Noguchi, N.; Nakada, M. Heterocycles2008, 76, 183-190.
    DOI: 10.3987/COM-08-S(N)29
  85. Catalytic Asymmetric Nozaki-Hiyama Reactions with A Tridentate Bis(oxazolinyl)carbazole Ligand
    Inoue, M.; Suzuki, T.; Kinoshita, A.; Nakada, M. Chem. Rec. 2008, 8, 169-181.
    DOI: 10.1002/tcr.20148
  86. Biomimetic Total Synthesis of (-)-Erinacine E
    Watanabe, H.; Nakada, M. J. Am. Chem. Soc. 2008, 130, 1150-1151.
    Synfacts, 2008, 564–564.
    *Published in JACS Select #1: Selected as one of the best of articles published in JACS in 2008.
    DOI: 10.1021/ja7102795
  87. Synthetic Studies on (-)-Scabronine A
    Watanabe, H.; Nakada, M. Tetrahedron Lett. 2008, 49, 1518-1522.
    DOI: 10.1016/j.tetlet.2007.12.109
  88. Construction of the Taxane Skeleton via the Stereoselective Conjugate Addition of Cyanide and the Intramolecular B-Alkyl Suzuki-Miyaura Coupling Reaction
    Utsugi, M.; Kamada, Y.; Miyamoto, H.; Nakada, M. Tetrahedron Lett. 2007, 48, 6868-6872.
    DOI: 10.1016/j.tetlet.2007.07.179
  89. Synthetic Studies on (-)-FR182877: Construction of the ABCD Ring System via the Intramolecular Cycloadditions (2)
    Tanaka, N.; Suzuki, T.; Hosoya, Y.; Nakada, M. Tetrahedron Lett. 2007, 48, 6488-6492.
    DOI: 10.1016/j.tetlet.2007.07.052
  90. Synthetic Studies on (-)-FR182877: Construction of the ABCD Ring System via the Intramolecular Cycloadditions (1)
    Suzuki, T.; Tanaka, N.; Matsumura, T.; Hosoya, Y.; Nakada, M. Tetrahedron Lett. 2007, 48, 6483-6487.
    DOI: 10.1016/j.tetlet.2007.07.051
  91. Synthetic Studies on Phloroglucins: A New Approach to the Bicyclo[3.3.1]nonane System via the Regioselective Ring-opening of the Methoxycyclopropane
    Abe, M.; Nakada, M. Tetrahedron Lett. 2007, 48, 4873-4877.
    DOI: 10.1016/j.tetlet.2007.05.041
  92. Highly Enantioselective Preparation of Tricyclo[4.4.0.05,7]decene Derivatives via Catalytic Asymmetric Intramolecular Cyclopropanation of α-Diazo-β-keto Esters
    Ida, R.; Nakada, M. Tetrahedron Lett. 2007, 48, 4855-4859.
    DOI: 10.1016/j.tetlet.2007.05.046
  93. Structure Elucidation and Enantioselective, Protecting Group-Free Total Synthesis of the HMG-CoA Reductase Inhibitor, FR901512 via Catalytic Asymmetric Nozaki−Hiyama Reactions
    Inoue, M.; Nakada, M. J. Am. Chem. Soc. 2007, 129, 4164-4165.
    Synfacts, 2007, 894–894.
    DOI: 10.1021/ja070812w
  94. New Preparation of Tridentate Bis-oxazoline Carbazole Ligand Effective for Enantioselective Nozaki-Hiyama Reaction
    Inoue, M.; Nakada, M. Heterocycles, 2007, 72, 133-138.
    DOI: 10.3987/COM-06-S(K)24
  95. Catalytic Asymmetric Intramolecular Cyclopropanation of 2-Diazo-3-oxo-6-heptenoic Acid Esters
    Takeda, H.; Honma M.; Ida R.; Sawada, T.; Nakada, M. Synlett, 2007, 579-582.
    DOI: 10.1002/chin.200728066
  96. Convergent Total Synthesis of (+)-Digitoxigenin via Catalytic Asymmetric Intramolecular Cyclopropanation
    Honma, M.; Nakada, M. Tetrahedron Lett. 2007, 48, 1541-1544.
    DOI: 10.1016/j.tetlet.2007.01.024
  97. Enantioselective Total Synthesis of (-)-Erinacine B
    Watanabe, H.; Takano, M.; Umino, A.; Ito, T.; Ishikawa, H.; Nakada, M. Org. Lett. 2007, 9, 359-362.
    DOI: 10.1021/ol0628816
  98. Studies on the Structure-enantioselectivity Relationships in the Catalytic Asymmetric Intramolecular Cyclopropanation Reaction of the α-Diazo-β-keto Sulfones Possessing a Methyl-substituted Phenyl Group
    Takeda, H.; Nakada, M. Tetrahedron: Asymmetry, 2006, 17, 2896-2906.
    DOI: 10.1016/j.tetasy.2006.10.046
  99. New Construction of the Bicyclo[3.3.1]nonane System via Lewis Acid Promoted Regioselective Ring-Opening Reaction of the Tricyclo[4.4.0.05,7]dec-2-ene Derivative
    Abe, M.; Nakada, M. Tetrahedron Lett. 2006, 47, 6347-6351.
    DOI: 10.1016/j.tetlet.2006.07.010
  100. Asymmetric Total Synthesis of Enantiopure (-)-Methyl Jasmonate via Catalytic Asymmetric Intramolecular Cyclopropanation of α-Diazo-β-keto Sulfone
    Takeda, H.; Watanabe, H.; Nakada, M. Tetrahedron, 2006, 62, 8054-8063.
    DOI: 10.1016/j.tet.2006.06.022
  101. Highly Stereoselective Construction of the Taxol C-Ring via SN2’ Reduction of an Allylic Phosphonium Salt
    Utsugi, M.; Miyano, M.; Nakada, M. Org. Lett. 2006, 8, 2973-2976.
    DOI: 10.1021/ol500431h
  102. Synthetic Studies on (+)-Ophiobolin A: Asymmetric Synthesis of the Spirocyclic CD-Ring Moiety
    Noguchi, N.; Nakada, M. Org. Lett. 2006, 8, 2039-2042.
    DOI: 10.1021/ol060437x
  103. Studies on the diastereoselectivity in the IMDA reactions of terminally activated (E,E,E)-nona-1,6,8-trienes
    Suzuki, T.; Tanaka, N.; Matsumura, T.; Hosoya, Y.; Nakada, M. Tetrahedron Lett. 2006, 47, 1593-1598.
    DOI: 10.1016/j.tetlet.2005.12.118
  104. Studies into Asymmetric Catalysis of Nozaki-Hiyama Allenylation
    Inoue, M.; Nakada, M. Angew. Chem., Int. Ed. Engl. 2006, 45, 252-255.
    DOI: 10.1002/anie.200502871
  105. A New Asymmetric Total Synthesis of Enantiopure (-)-Malyngolide
    Miyamoto, H.; Iwamoto, M.; Nakada, M. Heterocycles, 2005, 66, 61-68.
    DOI: 10.3987/COM-05-S(K)17
  106. Asymmetric Catalysis of Intramolecular Cyclopropanation of 5-Aryl-1-arylsulfonyl-1-diazo-5-hexene-2-ones
    Sawada, T.; Nakada, M. Adv. Synth. Catal. 2005, 347, 1527-1532.
    DOI: 10.1002/adsc.200505173
  107. Preparation of New Chiral Building Blocks: Highly Enantioselective Reduction of Prochiral 1,3-Cycloalkanediones Possessing a Methyl Group and a Protected Hydroxymethyl Group at their C2 Position with Baker's Yeast or CBS Catalyst
    Watanabe, H.; Iwamoto, M.; Nakada, M. J. Org. Chem. 2005, 70, 4652-4658.
    DOI: 10.1021/jo050349a
  108. Synthetic Studies on Erinacines: Enantioselective Total Synthesis of (+)-Allocyathin B2
     Takano, M.; Umino, A.; Nakada, M. Org. Lett. 2004, 6, 4897-4900.
    DOI: 10.1021/ol048010i
  109. Synthetic Studies on the Taxane Skeleton: Construction of Eight-membered Carbocyclic Rings by the Intramolecular B-Alkyl Suzuki-Miyaura Cross-coupling Reaction
    Kawada, H.; Iwamoto, M.; Utsugi, M.; Miyano, M.; Nakada, M. Org. Lett. 2004, 6, 4491-4494.
    DOI: 10.1021/ol0481939
  110. Synthetic Studies on the Seven and Eight-membered Rings by the Intramolecular Nozaki-Hiyama Reaction of the Allylic Phosphates
    Iwamoto, M.; Miyano, M.; Utsugi, M.; Kawada, H.; Nakada, M. Tetrahedron Lett. 2004, 45, 8653-8657.
    DOI: 10.1016/j.tetlet.2004.09.142
  111. Development of Silicon-tethered Anionic Reaction and Its Application to the Synthesis of Chiral A-ring Moieties of TaxolTM
    Iwamoto, M.; Miyano, M.; Utsugi, M.; Kawada, H.; Nakada, M. Tetrahedron Lett. 2004, 45, 8647-8651.
    DOI: 10.1016/j.tetlet.2004.09.143
  112. Studies on Catalytic Asymmetric Nozaki-Hiyama Propargylation
    Inoue, M.; Nakada, M. Org. Lett. 2004, 6, 2977-2980.
    DOI: 10.1021/ol048826j
  113. First Total Synthesis of Antimitotic Compound, (+)-Phomopsidin
    Suzuki, T.; Usui, K.; Miyake, Y.; Namikoshi, M.; Nakada, M. Org. Lett. 2004, 6, 553-556.
    DOI: 10.1021/ol036338q
  114. Enantioselective Intramolecular Cyclopropanation of α-Diazo-β-keto Sulfones: Asymmetric Synthesis of Bicyclo[4.1.0]heptanes and Tricyclo[4.4.0.0]decenes
    Honma, M.; Nakada, M. Tetrahedron Lett. 2003, 44, 9007-9011.
    DOI: 10.1016/j.tetlet.2003.09.215
  115. Preparation of New Chiral Building Blocks via Asymmetric Catalysis
    Iwamoto, M.; Kawada, H.; Tanaka, T.; Nakada, M. Tetrahedron Lett. 2003, 44, 7239-7243.
    DOI: 10.1016/j.tetlet.2003.08.009
  116. A New Asymmetric Tridentate Carbazole Ligand: Its Preparation and Application to Nozaki-Hiyama Allylation
    Suzuki, T.; Kinoshita, A.; Kawada, H.; Nakada, M. Synlett 2003, 570-572.
    DOI: 10.1055/s-2003-37535
  117. Asymmetric Catalysis on the Intramolecular Cyclopropanations of α-Diazo-β-keto Sulfones
    Honma, M.; Sawada, T.; Fujisawa, Y.; Utsugi, M.; Watanabe, H.; Umino, A.; Matsumura, T.; Hagihara, T.; Takano, M.; Nakada, M. J. Am. Chem. Soc. 2003, 125, 2860-2861.
    DOI: 10.1021/ja029534l
  118. A New Preparation of Cyclic Sulfates: A Highly 1,3-Asymmetric Induction in Halocyclosulfations
    Inoue, M.; Motomatsu, S.; Nakada, M. Synth. Commun. 2003, 33, 2857-2866.
    DOI: 10.1081/SCC-120022175
  119. Asymmetric Catalysis of Nozaki-Hiyama Allylation and Methallylation with A New Tridentate Bis(oxazolinyl)carbazole Ligand
    Inoue, M.; Suzuki, T.; Nakada, M. J. Am. Chem. Soc. 2003, 125, 1140-1141.
    DOI: 10.1021/ja021243p
  120. Synthetic Studies on FR182877: An Asymmetric Synthesis of the AB Ring Moiety of FR182877 via a Diastereoselective Intramolecular Diels-Alder Reaction
    Suzuki, T.; Nakada, M. Tetrahedron Lett. 2002, 43, 3263-3267.
    DOI: 10.1016/S0040-4039(02)00536-1
  121. Preparation of Novel Synthons, Uniquely Functionalized Tetrahydrofuran and Tetrahydropyran Derivatives
    Nakada, M.; Takano, M.; Iwata, Y. Chem. Pharm. Bull. 2000, 48, 1581-1585.
    DOI: 10.1248/cpb.48.1581
  122. Effect of Amines of the Selective Bromination of Some b-Substituted-2-butenoic Esters
    Nakada, M.; Kojima, E.; Ichinose, H. Synth. Commun. 2000, 30, 863-868.
    DOI: 10.1080/00397910008087098
  123. Reaction of Dianions of Acetoacetic Esters with Epibromohydrin Derivatives :
    A Novel Synthesis of Tetrahydrofuran Derivatives and Tetrahydropyran Derivatives
    Nakada, M.; Iwata, Y.; Takano, M. Tetrahedron Lett. 1999, 40, 9077-9080.
    DOI: 10.1016/S0040-4039(99)01913-9
  124. A Concise Synthetic Approach to Taxol C-ring Fragment
    Nakada, M.; Kojima, E.; Iwata, Y. Tetrahedron Lett. 1998, 39, 313-316.
    DOI: 10.1016/S0040-4039(97)10554-8
  125. Total Synthesis of Antitumor Macrolide, Rhizoxin and Chemistry of Acylsilane
    Nakada, M. Yakugaku Zasshi-J. Pharm. Soc. Jpn. 1997, 117, 486-508.
    DOI: 10.1248/yakushi1947.117.8_486
  126. Synthesis, Structure-activity Relationships, and Bioorganic Research of Homologs of Antitumor Macrolide, Rhizoxin Based on the Total Synthesis, and Development of Catalytic Asymmetric Synthesis for the Further Studies
    Nakada, M. Advances in Pharmaceutical Sciences, 1997, 13, 37-47.
    https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902197160124547
  127. Total Synthesis of (+)-Tautomycin
    Shimizu, S.; Nakamura, S.; Nakada, M.; Shibasaki, M. Tetrahedron, 1996, 52, 13363-13408.
    DOI: 10.1016/0040-4020(96)00811-3
  128. The First Chemical Synthesis of Wortmannin by Starting from Hydrocortisone
    Sato, S.; Nakada, M.; Shibasaki, M. Tetrahedron Lett. 1996, 37, 6141-6144.
    DOI: 10.1016/0040-4039(96)01332-9
  129. 17b-Hydroxy-16a-[125I]iodowortmannin, A Sensitive Labelling Agent for PI 3-Kinases
    Honzawa, S.; Nakada, M.; Kurosu, H.; Hazeki, O.; Katada, T.; Shibasaki, M. Chem. Pharm. Bull. 1995, 43, 2276-2278.
    DOI: 10.1248/cpb.43.2276
  130. Radiolabeling of Catalytic Subunits of PI 3-Kinases with 17b-Hydroxy-16a-[125I]iodowortmannin: Identification of Gbg-sensitive isoform as a complex composed of 46-kDa and 100-kDa subunits:
    Kurosu, H.; Hazeki, O.; Kukimoto, I.; Honzawa, S.; Shibasaki, M.; Nakada, M.; Ui, M.; Katada, T. Biochem. Biophys. Res. Commun. 1995, 216, 655-661.
    DOI: 10.1006/bbrc.1995.2672
  131. Total Synthesis of Taxol. 2. Construction of A and C Ring Intermediates and Initial Attempts to Construct the ABC Ring System:
    Nicolaou, K. C.; Liu, J.-J.; Yang, Z.; Ueno, H.; Sorensen, E. J.; Claiborne, C. F.; Guy, R. K.; Hwang, C.-K.; Nakada, M.; Nantermet, P. G. J. Am. Chem. Soc. 1995, 117, 634-644.
    DOI: 10.1021/ja00107a007
  132. Total Synthesis of Antitumor macrolide, Rhizoxin
    Nakada, M. J. Synth. Org. Chem. 1995, 53, 122-137.
    DOI: 10.5059/yukigoseikyokaishi.53.122
  133. Calicheamicin q1I: A Rationally Designed Molecule with Extremely Potent and Selective DNA Cleaving Properties and Apoptosis Inducing Activity:
    Nicolaou, K. C.; Li, T.; Nakada,M.; Hummel, C. W.; Hiatt, A.; Wrasidlo, W. Angew. Chem., Int. Ed. Engl. 1994, 33, 183-186.
    DOI: 10.1002/anie.199401831
  134. Non-chelation Controlled 1,3-Asymmetric Induction in b-Chiral Acylsilanes:
    Nakada, M.; Urano, Y.; Kobayashi, S.; Ohno, M. Tetrahedron Lett. 1994, 35, 741-744.
    DOI: 10.1016/S0040-4039(00)75805-9
  135. Synthesis of ABC Taxoid Ring Systems via a Convergent Strategy: Nicolaou, K. C.; Yang, Z.; Sorensen, E. J.; Nakada, M. J. Chem. Soc. Chem. Commun. 1993, 12, 1024-1026.
    DOI: 10.1039/C39930001024
  136. Total Synthesis of Calicheamicin g1I. 3. The Final Stages:
    Nicolaou, K. C.; Hummel, C. W.; Nakada, M.; Shibayama, K.; Pitsinos, E. N.; Saimoto, H.; Mizuno, Y.; Baldenius, K. -U.; Smith, A. L. J. Am. Chem. Soc. 1993, 115, 7625-7635.
    DOI: 10.1021/ja00070a006
  137. The First Total Synthesis of the Antitumor Macrolide, Rhizoxin:
    Nakada, M.; Kobayashi, S.; Shibasaki, M.; Iwasaki, S.; Ohno, M. Tetrahedron Lett. 1993, 34, 1039-1042.
    DOI: 10.1016/S0040-4039(00)77486-7
  138. Synthetic Study on an Antitumor Antibiotic Rhizoxin Using an Enzymatic Process on Prochiral b-Substituted Glutarates:
    Kobayashi, S.; Nakada, M.; Ohno, M. Indian J. Chem. 1993, 32B, 159-162.
    DOI: 10.1351/pac199264081121
  139. The First Total Synthesis of the Antitumor Macrolide Rhizoxin: Synthesis of the Key Building Blocks:
    Nakada, M.; Kobayashi, S.; Iwasaki, S.; Ohno, M. Tetrahedron Lett. 1993, 34, 1035-1038.
    DOI: 10.1016/S0040-4039(00)77485-5
  140. Total Synthesis of Calicheamicin g1I:
    Nicolaou, K. C.; Hummel, C. W.; Pitsinos, E. N.; Nakada, M.; Smith, A. L.; Shibayama, K.; Saimoto, H. J. Am. Chem. Soc. 1992, 114, 10082-10084.
    DOI: 10.1021/ja00051a063
  141. Synthetic Study on an Antitumor Antibiotic Rhizoxin Using an Enzymatic Process on Prochiral b-Substituted Glutarates:
    Kobayashi, S.; Nakada, M.; Ohno, M. Pure Appl. Chem. 1992, 64, 1121-1124.
    https://citeseerx.ist.psu.edu/document?repid=rep1&type=pdf&doi=a09dd72992cdba1ae3a816550039b0ec44130ad0
  142. A Novel Synthesis of Acylsilanes
    Nakada, M.; Nakamura, S.; Kobayashi, S.; Ohno, M. Tetrahedron Lett. 1991, 32, 4929-4932.
    DOI: 10.1016/S0040-4039(00)93499-3
  143. High Diastereofacial Selectivity in Nucleophilic Additions to Chiral Acylsilanes:
    Nakada, M.; Urano, Y.; Kobayashi, S. ; Ohno, M. J. Am. Chem. Soc. 1988, 110, 4826-4827.
    DOI: 10.1021/ja00222a050
  144. Enantioselective Hydrolysis of Dialkyl 3-Monosubstituted Glutarates with Pig Liver Esterase: Structure-Optical Purity Relationships
    Nakada, M.; Kobayashi, S.; Ohno, M.; Iwasaki, S.; Okuda, S. Tetrahedron Lett. 1988, 29, 3951-3954.
    DOI: 10.1016/S0040-4039(00)80391-3
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