発表論文

Iridium-Catalyzed Linear-Selective sp 3 C−H Alkylation ofN-Methylamides Using Alkenes Enabled by DiphosphiteLigands

Chem. Eur. J., 2026, e70913.

Haluhi Takahashi, Takanori Shibata*

Synthesis of Aryl-Substituted Hexa-Alkynyl Hexaazatrinaphthylenes via Sonogashira Coupling and Evaluation of Their Photophysical Properties

Chem. Asian J., 2026, 21e01003.

Yuchen Wu, Chisae Kumagai, Natsuhiko Sugimura, Takanori Shibata*

Tetraaza[7]-[15]helicenes Synthesized by Two-Step Strategy: Length-Controlled Chiral π-Systems Exhibiting Amplified Circularly Polarized Luminescence

Angew. Chem. Int. Ed., 2026, e24463

Takashi Otani*, Yuchen Wu, Kohei Ueda*, Yuki Ikeda, Yuna Tada, Natuna Kinoshita, Takanori Shibata*

Ir-Catalyzed Distal Branch- and Enantioselective Hydroarylation of Internal Alkenes Using Acetanilides via Chain-Walking and C–H Activation

Tetrahedron Letters, 2025, 173, 155823

Mizuki Kadota, King Hung Nigel Tang, Takanori Shibata*

Ir-Catalyzed Sulfur-Directed Vinylic C–H Activation for the Stereoselective Synthesis of 1,3-Dienes Using Alkynoates

Asian J. Org. Chem., 2025, e00192

Takanori Shibata*, Haru Marumo

Catalytic and Enantioselective Synthesis of Inherently Chiral Saddle-Shaped Compounds

Chem. Eur. J., 2025

Takanori Shibata*, Masahiro Nakada, Kosuke Senda, Mamoru Ito

Enantioselective Synthesis of Axially Chiral 1,8-Diarylnaphthalenes

Org. Lett., 2025, 27, 4524-4528

Takanori Shibata*, Hinako Nikawa, Ema Kadosaka, Mamoru Ito, Tohru Taniguchi, Kenji Monde

TfOH-catalyzed Markovnikov-selective hydrothiolation

Tetrahedron Letters, 2025, 160, 155550

Takanori Shibata*, Ryo Tokutake, Mamoru Ito

Ligand-Governed Regio- and Enantioselective [2+2+2] Cycloaddition

J. Am. Chem. Soc., 2025, 147, 6214–6226

King Hung Nigel Tang, Taichi Kishi, Natsuhiko Sugimura, Yuto Horio, Takanori Shibata*

Unconventional Ligand-to-Catalyst Ratio for Distal C–C Bond Formation

Adv. Synth. Catal., 2024, 366, 3610–3615

King Hung Nigel Tang, Haluhi Takahashi, Ryo Tokutake, Takanori Shibata*

Creation of a Chiral All-Carbon Quaternary Center

Org. Lett., 2024, 26, 5312–5317

Taiyo Yamamoto, Masayuki Asakura, Ken Yamanomoto, Takanori Shibata, Kohei Endo*

Ir-Catalyzed Distal Branch-Selective Hydroarylation of Unactivated Internal Alkenes with Benzanilides via C-H Activation along with Consecutive Isomerization

Org. Lett., 2023, 25, 5197–5202

King Hung Nigel Tang, Ryo Tokutake, Mamoru Ito, and Takanori Shibata*

Sulfide-Directed Ir-Catalyzed Vinylic sp² and Benzylic sp³ C-H Activation for the Construction of Sulfur-Containing Medium-Ring System

Chem. Eur. J., 2023, 29, e202300255, 1–5

Takahiro Iwaki, Haru Marumo, Mamoru Ito, Takanori Shibata*

Synthesis of Dithia[5]helicenes and Enantioselective Synthesis of Helically Chiral Thia[6]helicenes via Rh-Catalyzed Intramolecular [2 + 2 + 2] Cycloaddition of Triynes

J. Org. Chem., 2023, 88, 7703–7711

Shun Nishibe, Taichi Kishi, Mamoru Ito, and Takanori Shibata*

Experimental and Theoretical Evidence for Relativistic Catalytic Activity in C-H Activation of N-Phenylbenzamide Using a Cationic Iridium Complex

J. Phys. Chem. A., 2022, 126, 7627–7638

Chinami Takashima, Hisaki Kurita, Hideaki Takano, Yasuhiro Ikabata, Takanori Shibata, and Hiromi Nakai*

Ir-Catalyzed Intramolecular Cyclization of 2-Alkynyl Diaryl Sulfides for the Selective Synthesis of Sulfur-Containing Polycyclic Compounds

Adv. Synth. Catal., 2022, 364, 3472–3476

Takanori Shibata,* Takahiro Iwaki, Mamoru Ito

★ Selected as Inside cover ★

Synthesis of Hexaazatruxenes by Consecutive N-H/C-H Coupling Using a Hypervalent Iodine Reagent and Evaluation of Their Photophysical Properties

Eur. J. Org. Chem., 2022, e202200438, 1–6

Yuchen Wu, Takuma Sasayama, Takahiro Gotoh, Mamoru Ito, Takanori Shibata*

Synthesis of NHC Ligands Containing a Sulfoxide Moiety and Their Use in Cross-Coupling via a Au(I)/(III) Catalytic Cycle

Bull. Chem. Soc. Jpn., 2022, 95, 700–706

Takanori Shibata, *Rikako Nagai, Sari Okazaki, Shun Nishibe, and Mamoru Ito

★ Selected as Inside cover ★

Metal-Free Aerobic C-H Oxidation of Methylarenes to Aromatic Aldehydes by Sulfur-Containing Tetracyclic Compounds as Visible-Light Photocatalysts

Bull. Chem. Soc. Jpn., 2022, 95, 768–770

Takanori Shibata, *Mika Akino, Ayato Sekine and Mamoru Ito

Tail-To-Tail Stereoselective Dimerization of Acrylate Derivatives via Iridium-Catalyzed Vinylic sp2 C-H Activation

Adv. Synth. Catal., 2022, 364, 1666–1670

Masafumi Kojima, Mio Sasaki, Mamoru Ito, and Takanori Shibata*

Ir-Catalyzed Remote Functionalization by the Combination of Deconjugative Chain-Walking and C-H Activation Using a Transient Directing Group

Org. Lett., 2022, 24, 1313–1317

King Hung Nigel Tang, Kanako Uchida, Kazuki Nishihara, Mamoru Ito, and Takanori Shibata*

Gold-Catalyzed Cascade and Divergent Synthesis of Indolobenzazepines and Indoloquinolines from Nitrogen-Tethered 1,8-Diynes

Eur. J. Org. Chem., 2022, e202101337

Mamoru Ito, Hideaki Onoda, Asahi Takaki and Takanori Shibata

Pt(ii)-Chiral diene-catalyzed enantioselective formal [4 + 2] cycloaddition initiated by C-C bond cleavage and elucidation of a Pt(ii)/(iv) cycle by DFT calculations

Org. Chem. Front., 2021, 8, 6985-6991

Takanori Shibata, Natsumi Shiozawa, Shun Nishibe, Hideaki Takano and Satoshi Maeda

Ir-Catalyzed Enantioselective Formal C-H Conjugate Addition of Pyrrole and Indoles to α,β-Unsaturated Carbonyl Compounds

Org. Lett., 2021, 23, 9078-9082

Takanori Shibata, Mio Sasaki, Masafumi Kojima, and Mamoru Ito

Enantioselective Cross-Coupling of Electron-Deficient Alkenes via Ir-Catalyzed Vinylic sp2 C-H Alkylation

Org. Lett., 2021, 23, 8158-8162

Takanori Shibata, Masafumi Kojima, Sahoko Onoda, and Mamoru Ito

Ni-catalyzed non-activated C-S bond cleavage at ambient temperature for the synthesis of sulfur-containing polycyclic compounds

Chem. Commun., 2021, 57, 9048-9051

Takanori Shibata, Ayato Sekine, Mika Akino, and Mamoru Ito

Silver-Catalyzed C(sp3)-H Sulfonylation for the Synthesis of Benzyl Sulfones Using Toluene Derivatives and α-Amino Acid Sulfonamides

Bull. Chem. Soc. Jpn., 2021, 94, 1377-1384

Kyalo Stephen Kanyiva, Kanako Uchida and Takanori Shibata

Catalytic Synthesis of Dibenzazepines and Dibenzazocines by Selective Cycloisomerization

Eur. J. Org. Chem., 2021, 1688-1692

Mamoru Ito, Asahi Takaki, Moeka Okamura, Kyalo Stephen Kanyiva and Takanori Shibata

Synthesis and Chiroptical Properties of Quinoxaline-Fused Polyaza[5]-[7]helicenes with Orange-Color CPL Emissions

Helv. Chim. Acta, 2021, 104, e2100016

Takashi Otani, Takuma Sasayama, Masashi Horiuchi, Shunnosuke Okauchi, Hidetoshi Kawai, Maho Kitahara, Yoshitane Imai and Takanori Shibata

Palladium-Catalyzed sp3 C-H Benzoxylation of Alanine Derivatives Using Aldehydes

Synthesis, 2021, 53, 3085-3093

Kyalo Stephen Kanyiva, King Hung Nigel Tang, Jiarui Wang and Takanori Shibata

Gold-catalyzed dual C-C bond cleavage of biphenylenes bearing a pendant alkyne

Org. Biomol. Chem., 2020, 18, 5826-5831

Hideaki Takano, Sari Okazaki, Shun Nishibe, Takeharu Ito, Natsumi Shiozawa, Natsuhiko Sugimura, Kyalo Stephen Kanyiva and Takanori Shibata

Short-step synthesis and chiroptical properties of polyaza[5]-[9]helicenes

Chem. Commun., 2020, 56, 4484-4487

Takashi Otani, Takuma Sasayama, Chisaki Iwashimizu, Kyalo Stephen Kanyiva, Hidetoshi Kawai, and Takanori Shibata

Ir 触媒芳香族C-Hカップリング反応

「直接的芳香族カップリング反応の設計と応用」第5章、pp54-62

柴田 高範

Rhodium(I)-catalyzed reactions via carbon-hydrogen bond cleavage

“Rhodium Catalysis in Organic Synthesis” Edited by Ken Tanaka,, 2019, pp277–297

Takanori Shibata

ヘテロ原子を含む環状ポリアリレン類の触媒的不斉合成

有機合成化学協会誌, 2019, 77, 1005–1013

柴田高範

カチオン性イリジウム触媒を用いた均一系触媒反応における相対論効果

J. Comput. Chem., Jpn., 2019, 18, 136–138

髙島 千波, 五十幡 康弘, 栗田 久樹, 高野 秀明, 柴田 高範, 中井 浩巳

Catalytic Enantioselective Synthesis of Azepine-Fused Planar-Chiral Ferrocenes by Pt-Catalyzed Cycloisomerizations

Organometallics, 2019, 38, 4029–4035

Mamoru Ito, Moeka Okamura, Kyalo Stephen Kanyiva, Takanori Shibata

Iodine-Catalyzed Synthesis of Chiral 4-Imidazolidinones Using α-Amino Acid Derivatives via Dehydrogenative N-H/C(sp³)-H Coupling

J. Org. Chem., 2019, 84, 12773–12783

Kyalo Stephen Kanyiva, Marina Tane, Takanori Shibata

Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity

Chem. Sci., 2019, 10, 6715–6720

Akihito Mitake, Rikako Nagai, Ayato Sekine, Hideaki Takano, Natsuhiko Sugimura, Kyalo Stephen Kanyiva, Takanori Shibata

Recent Advances of Biphenylene: Synthesis, Reactions and Uses

Eur. J. Org. Chem., 2019, 2871–2883

Hideaki Takano, Takeharu Ito, Kyalo Stephen Kanyiva, Takanori Shibata

★ Selected as cover

Enantioselective Synthesis of Nine‐ to Eleven‐Membered Cyclic Polyphenylenes Containing Heteroatoms by Catalytic Intramolecular [2+2+2] Cycloaddition

Asian J. Org. Chem., 2019, 8, 970–977

Takanori Shibata, Toru Fusamae, Hideaki Takano, Natsuhiko Sugimura, Kyalo Stephen Kanyiva

Intramolecular Consecutive Dehydro‐Diels-Alder Reaction for the Catalytic and Enantioselective Construction of Axial Chirality

Angew. Chem. Int. Ed., 2018, 57, 15862–15865

Takanori Shibata, Ayato Sekine, Akihito Mitake, Kyalo Stephen Kanyiva

Regioselective Activation of a Sterically More Hindered C-C Bond of Biphenylenes Using an Alkene as Both a Directing Group and a Reaction Moiety

Chem. Eur. J., 2018, 24, 15173–15177

Hideaki Takano, Takeharu Ito, Kyalo Stephen Kanyiva, and Takanori Shibata

★ Selected as cover

Ir‐Catalyzed Enantioselective Intra‐ and Intermolecular Formal C-H Conjugate Addition to β‐Substituted α,β‐Unsaturated Esters

Asian J. Org. Chem., 2018, 7, 1411–1418

Takanori Shibata, Hisaki Kurita, Sahoko Onoda, Kyalo Stephen Kanyiva

α‐Amino Acid Sulfonamides as Versatile Sulfonylation Reagents: Silver‐Catalyzed Synthesis of Coumarins and Oxindoles by Radical Cyclization

Eur. J. Org. Chem., 2018, 5905–5909

Kyalo Stephen Kanyiva, Daisuke Hamada, Sohei Makino, Hideaki Takano, Takanori Shibata

★Selected as VIP(very important paper)

★ Selected as cover

8‐exo‐dig‐Selective Cycloisomerization for the Synthesis of Dibenzo[b,e][1,4]diazocines Using Cationic Au^I Catalysts

Eur. J. Org. Chem., 2018, 4740–4747

Mamoru Ito, Daisuke Inoue, Asahi Takaki, Kyalo Stephen Kanyiva, Takanori Shibata

Ir-Catalyzed Synthesis of Substituted Tribenzosilepins by Dehydrogenative C-H/Si-H Coupling

J. Org. Chem., 2018, 83, 3426–3432

Takanori Shibata, Ninna Uno, Tomoya Sasaki, Hideaki Takano, Tatsuki Sato, and Kyalo Stephen Kanyiva

Catalytic Dearomative Spirocyclization via Gold Carbene Species Derived from Ynamides: Efficient Synthesis of 2-Azaspiro[4.5]decan-3-ones

Chem. Eur. J., 2018, 24, 3721–3724

Mamoru Ito, Ryosuke Kawasaki, Kyalo Stephen Kanyiva and Takanori Shibata

Metal-Free N-H/C-H Coupling for Efficient Synthesis of Chiral Dihydroquinoxalinones From Readily Available α-Amino Acids

Eur. J. Org. Chem., 2018, 1067–1070

Kyalo Stephen Kanyiva, Masashi Horiuchi and Takanori Shibata

Silver-Catalyzed Efficient Synthesis of Oxindoles and Pyrroloindolines via α-Aminoalkylation of N-Arylacrylamides with Amino Acid Derivatives

Chem. Asian J., 2018, 13, 496–499

Kyalo Stephen Kanyiva, Sohei Makino and Takanori Shibata

★ Selected as cover

★Highlighted in ChemistryViewss

Cationic Au(I)-Catalyzed Cycloisomerization of N-(2-Alkynylphenyl)indolines for the Construction of Indolobenzazepine Skeleton

Heterocycles, 2017, 94, 2229–2246

Mamoru Ito, Daisuke Inoue, Ryosuke Kawasaki, Kyalo Stephen Kanyiva, Takanori Shibata

Enantioselective Synthesis of Sulfur-Containing Medium-Ring Heterocycles with Axial Chirality by Catalytic Intramolecular [2+2+2] Cycloaddition

Eur. J. Org. Chem., 2017, 7266–7270

Akihito Mitake, Toru Fusamae, Kyalo Stephen Kanyiva, Takanori Shibata

DFT Studies on the Mechanism of the Iridium-Catalyzed Formal [4 + 1] Cycloaddition of Biphenylene with Alkenes

ACS Omega, 2017, 2, 5228–5234

Hideaki Takano, Natsuhiko Sugimura, Kyalo Stephen Kanyiva, Takanori Shibata

Sulfur-Directed Carbon–Sulfur Bond Cleavage for Rh-Catalyzed Regioselective Alkynylthiolation of Alkynes

Chem. Commun., 2017, 53, 9016–9019

Takanori Shibata, Akihito Mitake, Yosuke Akiyama, Kyalo Stephen Kanyiva

Thermally Stable Monosubstituted Thiophene 1-Oxides and 1-Imides Stabilized by a Bulky Rind Group at the 3-Position: Synthesis, Structure, and Inversion Barriers on the Sulfur Atom

Bull. Chem. Soc. Jpn., 2017, 90, 697–705

Takashi Otani, Mayu Miyoshi, Takanori Shibata, Tsukasa Matsuo, Daisuke Hashizume, Kohei Tamao

★ Selected paper

Intramolecular C–H Alkenylation of N-Alkynylindoles: Exo- and Endo-Selective Cyclization Depending on the Metal Catalyst

Adv. Synth. Catal., 2017, 359, 1849–1853

Takanori Shibata, Takumi Baba, Hideaki Takano, Kyalo Stephen Kanyiva

★ VIP (Very Important Paper)

Facile Two-Step Synthesis of 1,10-Phenanthroline-Derived Polyaza[7]helicenes with High Fluorescence and CPL Efficiency

Angew. Chem. Int. Ed., 2017, 56, 3906–3910

Takashi Otani, Ami Tsuyuki, Taiki Iwachi, Satoshi Someya, Kotaro Tateno, Hidetoshi Kawai, Takao Saito, Kyalo Stephen Kanyiva, Takanori Shibata

★ Highlighted in Synfacts 2017 / SYNFACT of the Month

Catalytic Intramolecular [2+2+2] Cycloaddition of Peptide-Tethered Branched Triynes for the Synthesis of Cyclic Peptides

Heterocycles, 2017, 95, 1121–1131

Shuhei Obinata, Yu-ki Tahara, Kyalo Stephen Kanyiva, Takanori Shibata

Enantioselective Formal C–H Conjugate Addition of Acetanilides to β-Substituted Acrylates by Chiral Iridium Catalysts

Chem. Eur. J., 2017, 23, 88–91

Takanori Shibata, Masamichi Michino, Hisaki Kurita, Yu-ki Tahara, Kyalo Stephen Kanyiva

Point-to-Point Ultra-Remote Asymmetric Control with a Flexible Linker

Chem. Eur. J., 2017, 23, 282–285

Tsuneomi Kawasaki, Yasuyuki Ishikawa, Yoshihiro Minato, Takashi Otsuka, Shigeru Yonekubo, Itaru Sato, Takanori Shibata, Arimasa Matsumoto, Kenso Soai

Raman study on pentacene:C60 bulk heterojunction films

Vibrational Spectroscopy, 2016, 84, 133–138

Yasuhiro Iwasawa, Tomoya Sasaki, Takanori Shibata, Yukio Furukawa

Construction of a Polycyclic Conjugated System Containing a Dibenzazepine Moiety by Cationic Au(I)-Catalyzed Cycloisomerization

Eur. J. Org. Chem., 2016, 31, 5234–5237

Mamoru Ito, Ryosuke Kawasaki, Kyalo Stephen Kanyiva, Takanori Shibata

Enantioselective synthesis of planar-chiral 1,11-dioxa[11]paracyclophane-derived phosphoramidites and their use as chiral ligands

Tetrahedron: Asymmetry, 2016, 20–21, 1081–1087

Madhurima Hazra, Kyalo Stephen Kanyiva, Takanori Shibata

Pt-Catalyzed Enantioselective Cycloisomerization for the Synthesis of Planar-Chiral Ferrocene Derivatives

J. Org. Chem., 2016, 81, 6266–6272

Takanori Shibata, Ninna Uno, Tomoya Sasaki, Kyalo Stephen Kanyiva

Enantioselective Synthesis of Planar-Chiral 1,n-Dioxa[n]paracyclophane-Based Phosphites and Their Application as Chiral Ligands

Synthesis, 2016, 48, 2664–2670

Takanori Shibata, Miku Fukai, Ryosuke Sekine, Madhurima Hazra, Kyalo Stephen Kanyiva

Iridium-Catalyzed Formal [4 + 1] Cycloaddition of Biphenylenes with Alkenes Initiated by C–C Bond Cleavage for the Synthesis of 9,9-Disubstituted Fluorenes

Org. Lett., 2016, 18, 1860–1863

Hideaki Takano, Kyalo Stephen Kanyiva, Takanori Shibata

Catalytic and Enantioselective Synthesis of Chiral Multisubstituted Tribenzothiepins by Intermolecular Cycloadditions

Angew. Chem. Int. Ed., 2016, 55, 4552–4556

Yu-ki Tahara, Riku Matsubara, Akihito Mitake, Tatsuki Sato, Kyalo Stephen Kanyiva, Takanori Shibata

★ Highlighted in Synfacts 2016, 0488.

Enantioselective Synthesis of Aminoindan Carboxylic Acid Derivatives by the Catalytic Intramolecular [2+2+2] Cycloaddition of Amino Acid-Tethered Triynes

Eur. J. Org. Chem., 2016, 1405–1413

Yu-ki Tahara, Shuhei Obinata, Kyalo Stephen Kanyiva, Takanori Shibata, Attila Mandi, Tohru Taniguchi, Kenji Monde

Strategies for the Total Synthesis of Clavicipitic Acid

Chem. Eur. J., 2016, 22, 5468–5477

Mamoru Ito, Yu-ki Tahara, Takanori Shibata

Multi-Substituted Dibenzophosphole Oxide Synthesis by the Catalytic [2+2+2] Cycloaddition of Phosphoryl-Benzene-Tethered Diynes with Various Alkynes

Heterocycles, 2016, 93, 685–705

Yu-ki Tahara, Tatsuki Sato, Riku Matsubara, Kyalo Stephen Kanyiva, Takanori Shibata

有機分子の設計と機能性材料への応用

ファインケミカル, 2016, 45, 6–14

柴田 高範

Enantioselective sp3 C–H alkylation of γ-butyrolactam by a chiral Ir(I) catalyst for the synthesis of 4-substituted γ-amino acids

Chem. Commun., 2015, 51, 16660–16663

Tahara, Y.; Michino, M.; Ito, M.; Kanyiva, K. S.; Shibata, T.

Total Synthesis of cis-Clavicipitic Acid from Asparagine via Ir-Catalyzed C–H Bond Activation as a Key Step

Chem. Eur. J., 2015, 21, 11340–11343

Tahara, Y.; Ito, M.; Kanyiva, K. S.; Shibata, T.

★ Selected as Hot Topics of C–H activation in Wiley Journals

Ir-Catalyzed Intramolecular Enantioselective C–H Alkylation at the C2 Position of N-Alkenylindoles

Adv. Synth. Catal., 2015, 357, 1131–1135

Shibata, T.; Ryu, N.; Takano, H.

★ Selected as VIP
★ Inside Cover Picture

Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C–H silylation

Chem. Commun., 2015, 51, 7802–7804

Shibata, T.; Shizuno, T.; Sasaki, T.

★ Inside Back Cover Picture

Cationic Iridium-Catalyzed C–H Alkylation of 2-Substituted Pyridine N-Oxides with Acrylates

Org. Chem. Front., 2015, 2, 383–387

Shibata, T.; Takano, H.

Asymmetric synthesis of multi-substituted triptycenes via enantioselective alkynylation of 1,5-dibromoanthracene-9,10-dione

Tetrahedron: Asymmetry, 2015, 26, 41–45

Shibata, T.; Kamimura, Y.

[2+2+2] Cycloaddition of Sulfanylbenzene-Tethered Diynes with Alkynes for the Synthesis of Multi-Substituted Dibenzothiophene Derivatives

Heterocycles, 2015, 90, 1094–1110

Tahara, Y.; Matsubara, R.; Shibata, T.

(Special issue in honor of Prof. Isao Kuwajima)

Catalytic [2 + 2 + 2] Cycloaddition of Benzothiophene Dioxides with α,ω-Diynes for the Synthesis of Condensed Polycyclic Compounds

Org. Lett., 2014, 16, 5980–5983

Tahara, Y.; Gake, M.; Matsubara, R.; Shibata, T.

Synthesis of macrocyclic heteroarylenes by consecutive inter- and intramolecular cycloadditions of thiophenylene-tethered triynes

Tetrahedron, 2014, 70, 8453–8461

Shibata, T.; Fujimoto, M.; Otani, T.

★ Highlighted in Synfacts 2014, 1043

One-Pot Cross-Coupling of Diborylmethane for the Synthesis of Dithienylmethane Derivatives

Synlett, 2014, 25, 2184–2188

Endo, K.; Ishioka, T.; Shibata, T.

★ Highlighted in Synfacts 2014, 1265

Synthesis of Multicyclic Heterocycles Initiated by C–H Bond Activation Along with "Rollover" Using a Rh(III) Catalyst

Heteroatom Chem., 2014, 25, 379–388

Shibata, T.; Takayasu, S.

(Special issue in honor of Prof. Renji Okazaki)

Highly Chemo-, Enantio-, and Regioselective Synthesis of α,β-Disubstituted Furanones by Cu-Catalyzed Conjugate Addition

Chem. Eur. J., 2014, 20, 8893–8897

Endo, K.; Yakeishi, S.; Takayama, R.; Shibata, T.

★ Highlighted in Synfacts 2014, 1043

Directed C–H Alkenylation of Quinoline N-Oxides at the C-8 Position Using a Cationic Rhodium(I) Catalyst

Adv. Synth. Catal., 2014, 356, 1516–1520

Shibata, T.; Matsuo, Y.

Iridium-Catalyzed Enantioselective C–H Alkylation of Ferrocenes with Alkenes Using Chiral Diene Ligands

Angew. Chem. Int. Ed., 2014, 53, 5410–5413

Shibata, T.; Shizuno, T.

★ Highlighted in Synfacts 2014, 831

Ir(III)-Catalyzed C7-Position-Selective Oxidative C–H Alkenylation of Indolines with Alkenes in Air

Chem. Asian J., 2014, 9, 1257–1260

Pan, S.; Wakaki, T.; Ryu, N.; Shibata, T.

Iridium(I)-Catalyzed Direct C–H Bond Alkylation of the C-7 Position of Indolines with Alkenes

Adv. Synth. Catal., 2014, 356, 929–933

Pan, S.; Ryu, N.; Shibata, T.

★ Cover Picture

Enantioselective Synthesis of Planar-Chiral Phosphines with 1,N-Dioxa[N]paracyclophane Scaffold and Their Application as Chiral Ligands

Heterocycles, 2014, 88, 1355–1370

Kanda, K.; Ohshima, S.; Shizuno, T.; Hamanaka, R.; Fukai, M.; Shibata, T.

(Special issue in honor of Prof. Victor Snieckus)

Cationic Iridium-Catalyzed Synthesis Initiated by the Cleavage of C–H, N–H, and C–O Bonds

J. Synth. Org. Chem. Jpn. (English Edition), 2013, 71, 1182–1194 (Account)

T. Shibata, K. Tsuchikama, S. Pan

BINAM-mono-PHOS as New Entry for Multinuclear Cu-Catalysts in Asymmetric Conjugate Addition of Organozinc Reagents

Synlett, 2013, 24, 1155–1159

K. Endo, R. Takayama, T. Shibata

Functionalized BINOL-mono-PHOS for Multinuclear Cu-Catalysts in Asymmetric Conjugate Addition of Organozinc Reagents

Chem. Lett., 2013, 42, 547–549

K. Endo, S. Yakeishi, D. Hamada, T. Shibata

Ir(I)-Catalyzed Synthesis of N-Substituted Pyridones from 2-Alkoxypyridines via C–O Bond Cleavage

Org. Lett., 2013, 15, 1902–1905

S. Pan, N. Ryu, T. Shibata

Recent Advances in Iridium-Catalyzed Alkylation of C–H and N–H Bonds

ACS Catalysis, 2013, 3, 704–712

S. Pan, T. Shibata

Effect of Multinuclear Cu/Al-Complexes in Highly Asymmetric Conjugate Addition of Trimethylaluminum to Acyclic Enones

Angew. Chem. Int. Ed., 2013, 52, 606–610

K. Endo, D. Hamada, S. Yakeishi, T. Shibata

Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates

Beilstein J. Org. Chem., 2012, 8, 1844–1848

S. Takebayashi, T. Shizuno, T. Otani, T. Shibata

Ir(I)-Catalyzed C–H Bond Alkylation at the C2 Position of Indole with Alkenes

J. Am. Chem. Soc., 2012, 134, 17474–17477

S. Pan, N. Ryu, T. Shibata

Facile Synthesis of Cyclic Polyphenylenes via Consecutive Cycloadditions

Synthesis, 2012, 44, 3269–3284 (Feature Article)

T. Shibata, M. Fujimoto, H. Hirashima, T. Chiba, K. Endo

Rh(III)-Catalyzed C–H Activation via “Rollover” for 4-Azafluorenes

Org. Lett., 2012, 14, 5106–5109

T. Shibata, S. Takayasu, S. Yuzawa, T. Otani

Enantioselective Activation of Secondary sp3 C–H Bonds Adjacent to Nitrogen

Tetrahedron, 2012, 68, 9009–9015

S. Pan, Y. Matsuo, K. Endo, T. Shibata

One-Pot Synthesis of Diarylmethanes via Diborylmethane

J. Org. Chem., 2012, 77, 7223–7231 (Featured Article)

K. Endo, T. Ishioka, T. Ohkubo, T. Shibata

Reversal Enantioselectivity in Asymmetric Autocatalysis

Tetrahedron: Asymmetry, 2012, 23, 1023–1027

T. Shibata, H. Tarumi, T. Kawasaki, K. Soai

Ir-Catalyzed C–H Bond Functionalization of Ferrocenes

Organometallics, 2012, 31, 4114–4117

S. Takebayashi, T. Shibata

Cross Coupling between sp3 Carbons Using Diborylmethane

J. Org. Chem., 2012, 77, 4826–4831

K. Endo, T. Ohkubo, T. Ishioka, T. Shibata

Multinuclear Cu-Catalyzed Asymmetric Conjugate Addition

Org. Lett., 2012, 14, 2342–2345

K. Endo, D. Hamada, S. Yakeishi, M. Ogawa, T. Shibata

Detour and Direct Induction of Chiral Centers via C–H/C–C Formation

Synthesis, 2012, 44, 1427–1452 (Review)

K. Endo, T. Shibata

Ru-Catalyzed Enantioselective Addition of Amines to Styrenes

Org. Biomol. Chem., 2012, 10, 3815–3818

M. Otsuka, H. Yokoyama, K. Endo, T. Shibata

Enantioselective Synthesis of Cyclophanes via [2+2+2] Cycloaddition

Tetrahedron, 2012, 68, 2679–2686

T. Shibata, M. Miyoshi, T. Uchiyama, K. Endo, N. Miura, K. Monde

Ir-Catalyzed Regio- and Enantioselective Hydroamination of Alkenes

Org. Lett., 2012, 14, 780–783

S. Pan, K. Endo, T. Shibata

Asymmetric ortho-Lithiation of Paracyclophanes

Tetrahedron, 2012, 68, 1407–1416

K. Kanda, R. Hamanaka, K. Endo, T. Shibata

Highly Enantioselective Synthesis of Silahelicenes via Ir-Catalyzed [2+2+2]

Chem. Commun., 2012, 48, 1311–1313

T. Shibata, T. Uchiyama, Y. Yoshinami, S. Takayasu, K. Tsuchikama, K. Endo

Stereoselective Synthesis of Allylsilanes Bearing Tetrasubstituted Olefin via 2,2-Diborylethylsilane

Chem. Lett., 2011, 40, 1440–1442

Endo, K.; Sakamoto, A.; Ohkubo, T.; Shibata, T.

Cationic Ir(I)-Catalyzed sp³ C–H Bond Alkenylation of Ureas with Alkynes for the Synthesis of 2,3-Disubstituted Indoles

Synlett, 2011, 2171–2176

Shibata, T.; Hirashima, H.; Kasagawa, M.; Tsuchikama, K.; Endo, K.

Ir(I)-Catalyzed Enantioselective Secondary sp³ C–H Bond Activation of 2-(Alkylamino)pyridines with Alkenes

Org. Lett., 2011, 13, 4692–4695

Pan, S.; Endo, K.; Shibata, T.

Ir(III)-Catalyzed Room-Temperature Synthesis of Multisubstituted Benzofurans Initiated by C–H Activation of α-Aryloxy Ketones

Synlett, 2011, 2075–2079

Shibata, T.; Hashimoto, Y.-k.; Otsuka, M.; Tsuchikama, K.; Endo, K.

Regioselective Addition of Various Heteronucleophiles to (Styrene)Cr(CO)₃ Complexes

Organometallics, 2011, 30, 3683–3685

Otsuka, M.; Endo, K.; Shibata, T.

Facile Catalytic SNAr Reaction of Nonactivated Fluoroarenes with Amines Using η⁶-Benzene Ru(II) Complex

Synlett, 2010, 2601–2606

Otsuka, M.; Yokoyama, H.; Endo, K.; Shibata, T.

Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp³-Carbon in 1,1-Diborylalkanes at Room Temperature

J. Am. Chem. Soc., 2010, 132, 11033–11035

Endo, K.; Ohkubo, T.; Hirokami, M.; Shibata, T.

Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates

J. Org. Chem., 2010, 75, 3469–3472

Endo, K.; Hirokami, M.; Shibata, T.

Multinuclear Catalyst for Copper-Catalyzed Asymmetric Conjugate Addition of Organozinc Reagents

Angew. Chem. Int. Ed., 2010, 49, 2410–2413

Endo, K.; Ogawa, M.; Shibata, T.

Iridium-Catalyzed Selective Synthesis of 4-Substituted Benzofurans and Indoles via Directed Cyclodehydration

Adv. Synth. Catal., 2009, 351, 2850–2854

Tsuchikama, K.; Hashimoto, Y.; Endo, K.; Shibata, T.

Catalytic Enantioselective Synthesis of Chiral Tetraphenylenes: Consecutive Inter- and Intramolecular Cycloadditions of Two Triynes

Angew. Chem. Int. Ed., 2009, 48, 8066–8069

Shibata, T.; Chiba, T.; Hirashima, H.; Ueno, Y.; Endo, K.

Enantioselective Synthesis of Chiral Tripodal Cage Compounds by [2 + 2 + 2] Cycloaddition of Branched Triynes

Org. Lett., 2009, 11, 3906–3908

Shibata, T.; Uchiyama, T.; Endo, K.

Synthesis of 1,1-Organodiboronates via Rh(I)Cl-Catalyzed Sequential Regioselective Hydroboration of 1-Alkynes

Synlett, 2009, 1331–1335

Endo, K.; Hirokami, M.; Shibata, T.

Cationic Ir(I)-Catalyzed sp³ C–H Bond Alkenylation of Amides with Alkynes

Org. Lett., 2009, 11, 1821–1823

Tsuchikama, K.; Kasagawa, M.; Endo, K.; Shibata, T.

The First Asymmetric Sonogashira Coupling for the Enantioselective Generation of Planar Chirality in Paracyclophanes

Chem. Commun., 2009, 1870–1872

Kanda, K.; Koike, T.; Endo, K.; Shibata, T.

DMAP-Accelerated Rhodium(I) Chloride Catalyzed Hydroboration of Vinyl Arenes

Synlett, 2008, 30, 3231–3233

K. Endo, M. Hirokami, K. Takeuchi, T. Shibata

Cationic Iridium–BINAP Complex-Catalyzed Addition of Aryl Ketones to Alkynes and Alkenes via Directed C–H Bond Cleavage

J. Organomet. Chem., 2008, 693, 3939–3942

K. Tsuchikama, M. Kasagawa, Y. Hashimoto, K. Endo, T. Shibata

Highly Diastereo- and Enantioselective Construction of Both Central and Axial Chiralities by Rh-Catalyzed [2+2+2] Cycloaddition

Org. Biomol. Chem., 2008, 6, 4296–4298

T. Shibata, M. Otomo, Y. Tahara, K. Endo

Counteranion-Accelerated Rh(OAc)-Catalyzed Regioselective Hydroboration of Vinylarenes

Organometallics, 2008, 27, 5390–5393

K. Endo, M. Hirokami, T. Shibata

Rhodium-Catalyzed Intramolecular Cycloaddition of Cyclopropene-Ynes Triggered by Carbon–Carbon Bond Cleavage

Heterocycles, 2008, 76, 1261–1270

T. Shibata, S. Maekawa, K. Tamura

Catalytic Synthesis of Chiral Cyclic Compounds by Enantioselective Cycloaddition

Fainkemikaru, 2008, 37, 55–67 (Account)

T. Shibata, K. Tsuchikama

Recent Advances in Enantioselective [2+2+2] Cycloaddition

Org. Biomol. Chem., 2008, 1317–1323 (Account)

T. Shibata, K. Tsuchikama

Iridium-Catalyzed Enantioselective Formal [4+2] Cycloaddition of Biphenylene and Alkynes for the Construction of Axial Chirality

Synlett, 2008, 765–768

T. Shibata, G. Nishizawa, K. Endo

Enantioselective Syntheses of Various Chiral Multicyclic Compounds with Quaternary Carbon Stereocenters by Catalytic Intramolecular Cycloaddition

J. Am. Chem. Soc., 2008, 130, 3451–3457

T. Shibata, Y. Tahara, K. Tamura, K. Endo

Carbonylative and Hydrosilylative Carbocyclization of 1,5-Diynes for the Synthesis of Cyclic Dienones

Organometallics, 2008, 27, 1342–1344

T. Shibata, N. Nakagawa, Y. Ueno, K. Endo

Rh-Catalyzed Intermolecular and Enantioselective [4+2] Cycloaddition of 1,3-Dienes with Dimethyl Acetylenedicarboxylate

Org. Biomol. Chem., 2008, 6, 464–467

T. Shibata, D. Fujiwara, K. Endo

Iridium-Catalyzed Consecutive and Enantioselective [2+2+2] Cycloaddition of Tetraynes and Hexaynes for the Construction of Axially Chiral Biaryl System

Tetrahedron, 2008, 64, 821–830

T. Shibata, S. Yoshida, Y. Arai, M. Otsuka, K. Endo

Rhodium-Catalyzed Enantioselective [2+2+2] Cycloaddition of Diynes with Unfunctionalized Alkene

Tetrahedron, 2007, 63, 12853–12859

T. Shibata, A. Kawachi, M. Ogawa, Y. Kuwata, K. Tsuchikama, K. Endo

Chiral Secondary Alcohol-Induced Asymmetric Autocatalysis: Correlation between the Absolute Configuration of the Chiral Initiators and the Product Chiral Ortho-Diarylbenzene Derivatives

Tetrahedron: Asymmetry, 2007, 18, 1759–1762

T. Shibata, K. Iwahashi, T. Kawasaki, K. Soai

Enantioselective [2+2+2] Cycloaddition of Endiynes for the Synthesis of Chiral Cyclohexa-1,3-dienes

J. Org. Chem., 2007, 72, 6521–6525

T. Shibata, H. Kurokawa, K. Kanda

Rh-Catalyzed Cyclization of Diynes and Enynes Initiated by Carbonyl-Directed Activation of Aromatic and Vinylic C–H Bonds

Org. Lett., 2007, 9, 3097–3099

K. Tsuchikama, Y. Kuwata, Y. Tahara, Y. Yoshinami, T. Shibata

Rhodium Complex-Catalyzed [2+2+2] Cycloaddition of Diynes and Carbonyl Compounds

Synlett, 2007, 1395–1398

K. Tsuchikama, Y. Yoshinami, T. Shibata

Iridium-Catalyzed Enantioselective [2+2+2] Cycloaddition of Diynes and Monoalkynes for the Generation of Axial Chiralities

Adv. Synth. Catal., 2006, 348, 2475–2483

T. Shibata, Y. Arai, K. Takami, K. Tsuchikama, T. Fujimoto, S. Takebayashi, K. Takagi

Recent Advances in the Catalytic Pauson–Khand-Type Reaction

Adv. Synth. Catal., 2006, 348, 2328–2336 (Review)

T. Shibata

Highly Enantioselective Construction of a Chiral Spirocyclic Structure by the [2+2+2] Cycloaddition of Diynes and exo-Methylene Cyclic Compounds

J. Am. Chem. Soc., 2006, 128, 13686–13687

K. Tsuchikama, Y. Kuwata, T. Shibata

Iridium and Rhodium Complex-Catalyzed Cycloadditions

J. Synth. Org. Chem., Jpn., 2006, 64, 913–922 (Account)

T. Shibata

Enantioselective Intramolecular [2+2+2] Cycloaddition of 1,4-Diene-Ynes: A New Approach to the Construction of Quaternary Carbon Stereocenters

J. Am. Chem. Soc., 2006, 128, 11766–11767

T. Shibata, Y. Tahara

Cationic Au(I)- and Pt(II)-Catalyzed Silylation of Alcohols Using Allylsilane

Bull. Chem. Soc. Jpn., 2006, 79, 1146–1147

T. Shibata, K. Kanda, Y. Ueno, R. Fujiwara

Enantioselective Intramolecular [2+2+2] Cycloaddition of Triynes for the Synthesis of Atropisomeric Chiral Ortho-Diarylbenzene Derivatives

Tetrahedron: Asymmetry, 2006, 17, 614–619

T. Shibata, K. Tsuchikama, M. Otsuka

Rh-Catalyzed Enantioselective [2+2] Cycloaddition of Alkynyl Esters and Norbornene Derivatives

Org. Lett., 2006, 8, 1343–1345

T. Shibata, K. Takami, A. Kawachi

Cationic Au(I)-Catalyzed Cycloisomerization of Aromatic Enynes for the Synthesis of Substituted Naphthalenes

Synlett, 2006, 411–414

T. Shibata, Y. Ueno, K. Kanda

Ir-Catalyzed Almost Perfect Enantioselective Synthesis of Helical Polyaryls Based on an Axially Chiral Sequence

Chem. Commun., 2005, 6017–6019

T. Shibata, K. Tsuchikama

Enantioselective Construction of Quaternary Carbon Centers by Catalytic [2+2+2] Cycloaddition of 1,6-Enynes and Alkynes

Org. Lett., 2005, 7, 4955–4957

Shibata, T.; Arai, Y.; Tahara, Y.

Iridium-catalyzed Enantioselective Pauson-Khand-Type Reaction of 1,6-Enynes

Tetrahedron, 2005, 61, 9974–9979

Shibata, T.; Toshida, N.; Yamasaki, M.; Maekawa, S.; Takagi, K.

Iridium-catalyzed Enantioselective Cycloisomerization of Nitrogen-Bridged 1,6-Enynes to 3-Azabicyclo[4.1.0]heptenes

Tetrahedron, 2005, 61, 9018–9024

Shibata, T.; Kobayashi, Y.; Maekawa, S.; Toshida, N.; Takagi, K.

Thermal and Au(I)-Catalyzed Intramolecular [4+2] Cycloaddition of Aryl-Substituted 1,6-Diynes for the Synthesis of Biaryl Compounds

Synlett, 2005, 2062–2066

Shibata, T.; Fujiwara, R.; Takano, D.

Cationic Platinum-Catalyzed Etherification by Intra- and Intermolecular Dehydration of Alcohols

Synlett, 2005, 152–154

Shibata, T.; Fujiwara, R.; Ueno, Y.

The Reaction of Butatrienolates with Aldehydes for the Syntheses of α-Vinylidene Acylsilanes

Bull. Chem. Soc. Jpn., 2004, 77, 1937–1938

Shibata, T.; Takami, K.; Arai, Y.; Tsuchikama, K.; Maekawa, S.

Iridium Complex-Catalyzed Highly Enantio- and Diastereoselective [2+2+2] Cycloaddition for the Synthesis of Axially Chiral Teraryl Compounds

J. Am. Chem. Soc., 2004, 126, 8382–8383

Shibata, T.; Fujimoto, T.; Yokota, K.; Takagi, K.