Publications

2025-
2024(2)
2023(3)
2022(8)
2021(11)
2020(4)
2019(11)
2018(9)
2017(10)
2016 (11)
2015 (7)
2014 (10)
2013 (6)
2012 (16)
2011 (9)
2010 (8)
2009 (6)
2008 (12)
2007 (5)
2006 (9)
2005 (6)
2004 (2)

    2025

  1. NEW! Ir-Catalyzed Sulfur-Directed Vinylic C─H Activation for the Stereoselective Synthesis of 1,3-Dienes Using Alkynoates
    Takanori Shibata*, and Haru Marumo Asian J. Org. Chem., 2025, e00192.
  2. Catalytic and Enantioselective Synthesis of Inherently Chiral Saddle-Shaped Compounds by [2 + 2 + 2] Cycloaddition of 1,8-Naphthylene-Based 1,10-Diynes with Alkynoates
    Takanori Shibata*, Masahiro Nakada, Kosuke Senda, and Mamoru Ito Chem. Eur. J., 2025, e202501193.
  3. Enantioselective Synthesis of Axially Chiral 1,8-Diarylnaphthalenes by Rh-Catalyzed [2 + 2 + 2] Cycloaddition and Evaluation of Their Chiroptical Properties
    Takanori Shibata*, Hinako Nikawa, Ema Kadosaka, Mamoru Ito, Tohru Taniguchi, and Kenji Monde Org. Lett., 2025, 27, 4524-4528.
  4. TfOH-catalyzed Markovnikov-selective hydrothiolation of tri- and tetrasubstituted alkenes
    Takanori Shibata*, Ryo Tokutake, and Mamoru Ito Tetrahedron Letters, 2025, 160, 155550.
  5. Ligand-Governed Regio- and Enantioselective [2 + 2 + 2] Cycloaddition of 1,7-Enynes: Assembly of the Benzo[c]chromen-1-ol Backbone and Access to Enantioenriched Cannabinol Bioisostere
    King Hung Nigel Tang, Taichi Kishi, Natsuhiko Sugimura, Yuto Horio, and Takanori Shibata* J. Am. Chem. Soc., 2025, 147, 6214-6226.
    ★大学のプレスリリースで紹介されました★

    6. 2024

  6. Unconventional Ligand-to-Catalyst Ratio for the Distal C-C Bond Formation via C-H Activation and Chain-Walking
    King Hung Nigel Tang, Haluhi Takahashi, Ryo Tokutake, and Takanori Shibata* Adv. Synth. Catal., 2024, 366, 3610-3615.
  7. Creation of a Chiral All-Carbon Quaternary Center Induced by CF3 and CH3 Substituents via Cu-Catalyzed Asymmetric Conjugate Addition
    Taiyo Yamamoto, Masayuki Asakura, Ken Yamanomoto, Takanori Shibata, and Kohei Endo* Org. Lett., 2024, 26, 5312-5317

    8. 2023

  8. Ir-Catalyzed Distal Branch-Selective Hydroarylation of Unactivated Internal Alkenes with Benzanilides via C-H Activation along with Consecutive Isomerization
    King Hung Nigel Tang, Ryo Tokutake, Mamoru Ito, and Takanori Shibata* Org. Lett., 2023, 25, 5197-5202
  9. Sulfide-Directed Ir-Catalyzed Vinylic sp2 and Benzylic sp3 C-H Activation for the Construction of Sulfur-Containing Medium-Ring System
    Takahiro Iwaki, Haru Marumo, Mamoru Ito, Takanori Shibata* Chem. Eur. J., 2023, 29, e202300255, 1-5
  10. Synthesis of Dithia[5]helicenes and Enantioselective Synthesis of Helically Chiral Thia[6]helicenes via Rh-Catalyzed Intramolecular [2 + 2 + 2] Cycloaddition of Triynes
    Shun Nishibe, Taichi Kishi, Mamoru Ito, and Takanori Shibata* J. Org. Chem., 2023, 88, 7703-7711

    11. 2022

  11. Experimental and Theoretical Evidence for Relativistic Catalytic Activity in C-H Activation of N-Phenylbenzamide Using a Cationic Iridium Complex
    Chinami Takashima, Hisaki Kurita, Hideaki Takano, Yasuhiro Ikabata, Takanori Shibata, and Hiromi Nakai* J. Phys. Chem. A., 2022, 126, 7627-7638
  12. Ir-Catalyzed Intramolecular Cyclization of 2-Alkynyl Diaryl Sulfides for the Selective Synthesis of Sulfur-Containing Polycyclic Compounds
    Takanori Shibata,* Takahiro Iwaki, Mamoru Ito Adv. Synth. Catal., 2022, 364, 3472-3476
    ★Selected as Inside cover★
  13. Synthesis of Hexaazatruxenes by Consecutive N-H/C-H Coupling Using a Hypervalent Iodine Reagent and Evaluation of Their Photophysical Properties
    Yuchen Wu, Takuma Sasayama, Takahiro Gotoh, Mamoru Ito, Takanori Shibata* Eur. J. Org. Chem., 2022, e202200438, 1-6
  14. Synthesis of NHC Ligands Containing a Sulfoxide Moiety and Their Use in Cross-Coupling via a Au(I)/(III) Catalytic Cycle
    Takanori Shibata, *Rikako Nagai, Sari Okazaki, Shun Nishibe, and Mamoru Ito Bull. Chem. Soc. Jpn., 2022, 95, 700-706
    ★Selected as Inside cover★
  15. Metal-Free Aerobic C-H Oxidation of Methylarenes to Aromatic Aldehydes by Sulfur-Containing Tetracyclic Compounds as Visible-Light Photocatalysts
    Takanori Shibata, *Mika Akino, Ayato Sekine and Mamoru Ito Bull. Chem. Soc. Jpn., 2022, 95, 768-770
  16. Tail-To-Tail Stereoselective Dimerization of Acrylate Derivatives via Iridium-Catalyzed Vinylic sp2 C-H Activation
    Masafumi Kojima, Mio Sasaki, Mamoru Ito, and Takanori Shibata* Adv. Synth. Catal., 2022, 364, 1666-1670
  17. Ir-Catalyzed Remote Functionalization by the Combination of Deconjugative Chain-Walking and C-H Activation Using a Transient Directing Group
    King Hung Nigel Tang, Kanako Uchida, Kazuki Nishihara, Mamoru Ito, and Takanori Shibata* Org. Lett., 2022, 24, 1313-1317
  18. Gold-Catalyzed Cascade and Divergent Synthesis of Indolobenzazepines and Indoloquinolines from Nitrogen-Tethered 1,8-Diynes
    Mamoru Ito, Hideaki Onoda, Asahi Takaki and Takanori Shibata Eur. J. Org. Chem., 2022 , e202101337

    19. 2021

  19. Pt(ii)-Chiral diene-catalyzed enantioselective formal [4 + 2] cycloaddition initiated by C-C bond cleavage and elucidation of a Pt(ii)/(iv) cycle by DFT calculations
    Takanori Shibata, Natsumi Shiozawa, Shun Nishibe, Hideaki Takano and Satoshi Maeda Org. Chem. Front., 2021, 8, 6985-6991
  20. Ir-Catalyzed Enantioselective Formal C-H Conjugate Addition of Pyrrole and Indoles to α,β-Unsaturated Carbonyl Compounds
    Takanori Shibata, Mio Sasaki, Masafumi Kojima, and Mamoru Ito Org. Lett., 2021,23, 9078-9082
  21. Enantioselective Cross-Coupling of Electron-Deficient Alkenes via Ir-Catalyzed Vinylic sp2 C-H Alkylation
    Takanori Shibata, Masafumi Kojima, Sahoko Onoda, and Mamoru Ito Org. Lett., 2021, 23, 8158-8162
  22. Ni-catalyzed non-activated C-S bond cleavage at ambient temperature for the synthesis of sulfur-containing polycyclic compounds
    Takanori Shibata, Ayato Sekine, Mika Akino, and Mamoru Ito Chem. Commun., 2021, 57, 9048-9051
    23. ★Selected as Back cover★
  23. Silver-Catalyzed C(sp3)-H Sulfonylation for the Synthesis of Benzyl Sulfones Using Toluene Derivatives and α-Amino Acid Sulfonamides
    Kyalo Stephen Kanyiva, Kanako Uchida and Takanori Shibata Bull. Chem. Soc. Jpn., 2021, 94, 1377-1384
    ★Selected as Inside cover★
  24. 遷移金属触媒によるビフェニレン類の変換反応の開発と多環式炭化水素合成への展開
    高野秀明, 柴田高範 有機合成化学協会誌 2021, 79, 849-858
  25. Catalytic Synthesis of Dibenzazepines and Dibenzazocines by 7‐Exo‐ and 8‐Endo‐Dig‐Selective Cycloisomerization
    Mamoru Ito, Asahi Takaki, Moeka Okamura, Kyalo Stephen Kanyiva and Takanori Shibata Eur. J. Org. Chem. 2021, 1688-1692
  26. Synthesis and Chiroptical Properties of Quinoxaline‐Fused Polyaza[5]-[7]helicenes with Orange‐Color CPL Emissions
    Takashi Otani, Takuma Sasayama, Masashi Horiuchi, Shunnosuke Okauchi, Hidetoshi Kawai, Maho Kitahara, Yoshitane Imai and Takanori Shibata Helv. Chim. Acta, 2021, 104, e2100016
  27. Palladium-Catalyzed sp3 C-H Benzoxylation of Alanine Derivatives Using Aldehydes under Ambient Conditions
    Kyalo Stephen Kanyiva, King Hung Nigel Tang, Jiarui Wang and Takanori Shibata Synthesis, 2021, 53, 3085-3093
  28. Metal‐Free Aminoiodination of Alkynes Under Visible Light Irradiation for the Construction of a Nitrogen‐Containing Eight‐Membered Ring System
    Kyalo Stephen Kanyiva, Tane Marina, Shun Nishibe and Takanori Shibata Adv. Synth. Catal. , 2021, 363, 2746-2751

    29. 2020

  29. Gold-catalyzed dual C-C bond cleavage of biphenylenes bearing a pendant alkyne at ambient temperature
    Hideaki Takano, Sari Okazaki, Shun Nishibe, Takeharu Ito, Natsumi Shiozawa, Natsuhiko Sugimura, Kyalo Stephen Kanyiva and Takanori Shibata Org. Biomol. Chem., 2020, 18, 5826-5831 Advance Article
  30. Short-step synthesis and chiroptical properties of polyaza[5]-[9]helicenes with blue to green-colour emission
    Takashi Otani, Takuma Sasayama, Chisaki Iwashimizu, Kyalo Stephen Kanyiva, Hidetoshi Kawai, and Takanori Shibata Chem. Commun., 2020, 56, 4484-4487
  31. Catalytic Enantioselective Synthesis of Axially Chiral Polycyclic Aromatic Hydrocarbons (PAHs) via Regioselective C-C Bond Activation of Biphenylenes
    Hideaki Takano, Natsumi Shiozawa, Yoshitane Imai, Kyalo Stephen Kanyiva, and Takanori Shibata J. Am. Chem. Soc., 2020, 142, 4714-4722
    32. ★Selected as cover picture★
    ★Highlighted in Synfacts 2020, 16(06), 0664.★
    ★大学のプレスリリースで紹介されました★
  32. Gold(I)-Catalyzed 10-endo-dig-Selective Cycloisomerization of N-(2-Anilinobenzyl)propargylamines
    Mamoru Ito, Daisuke Inoue, Asahi Takaki, Kyalo Stephen Kanyiva, and Takanori Shibata Heterocycles, 2020, 101, 195-208

    33. 2019

  33. Ir 触媒芳香族C－H カップリング反応
    柴田　高範 「直接的芳香族カップリング反応の設計と応用」第5章、pp54-62
  34. Rhodium(I)-catalyzed reactions via carbon-?hydrogen bond cleavage
    Takanori Shibata, “Rhodium Catalysis in Organic Synthesis” Edited by Ken Tanaka, 2019, pp277-297
  35. ヘテロ原子を含む環状ポリアリレン類の触媒的不斉合成
    柴田 高範, 有機合成化学協会誌、2019, 77, 1005-1013
  36. カチオン性イリジウム触媒を用いた均一系触媒反応における相対論効果
    髙島 千波, 五十幡 康弘, 栗田 久樹, 高野 秀明, 柴田 高範, 中井 浩巳 J. Comput. Chem., Jpn., 2019, 18, 136-138.
  37. Catalytic Enantioselective Synthesis of Azepine-Fused Planar-Chiral Ferrocenes by Pt-Catalyzed Cycloisomerizations
    Mamoru Ito, Moeka Okamura, Kyalo Stephen Kanyiva, and Takanori Shibata Organometallics, 2019, 38, 4029-4035. (Special Issue of "Asymmetric Synthesis Enabled by Organometallic Complexes”)
  38. Iodine-Catalyzed Synthesis of Chiral 4-Imidazolidinones Using α-Amino Acid Derivatives via Dehydrogenative N-H/C(sp3)-H Coupling
    Kyalo Stephen Kanyiva, Marina Tane, Takanori Shibata, J. Org. Chem., 2019, 84, 12773-12783.
  39. Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity
    Akihito Mitake, Rikako Nagai, Ayato Sekine, Hideaki Takano, Natsuhiko Sugimura, Kyalo Stephen Kanyiva, and Takanori Shibata Chem. Sci., 2019, 10, 6715-6720
  40. Recent Advances of Biphenylene: Synthesis, Reactions and Uses
    Hideaki Takano, Takeharu Ito, Kyalo Stephen Kanyiva, Takanori Shibata Eur. J. Org. Chem., 2019, 57, 2871-2883 (minireview)
    ★Selected as cover picture★
  41. Enantioselective Synthesis of Nine‐ to Eleven‐Membered Cyclic Polyphenylenes Containing Heteroatoms by Catalytic Intramolecular [2+2+2] Cycloaddition
    Takanori Shibata, Toru Fusamae, Hideaki Takano, Natsuhiko Sugimura, Kyalo Stephen Kanyiva Asian J. Org. Chem., 2019, 8, 970-977 (Special Issue on Heterocyclic Chemistry)
  42. Synthesis of Indolo[1,2-a]indole Derivatives by Cationic Au(I)-catalyzed Exo-selective Cycloisomerization and Their Photophysical Properties
    Madhurima Hazra, Daisuke Inoue, Mamoru Ito, Kyalo Stephen Kanyiva, and Takanori Shibata Heterocycles., 2019, 99, 1412-1422, Accepted in Special issue for the celebration of Prof. Toru Fukuyama on his 70th birthday
    ★Highlighted in Synfacts 2019, 0350.★

    43. 2018

  43. Intramolecular Consecutive Dehydro‐Diels-Alder Reaction for the Catalytic and Enantioselective Construction of Axial Chirality
    Takanori Shibata, Ayato Sekine, Akihito Mitake, Kyalo Stephen Kanyiva Angew. Chem. Int. Ed., 2018, 57, 15862-15865
    ★Highlighted in Synfacts 2019, 0350.★
  44. Regioselective Activation of a Sterically More Hindered C-C Bond of Biphenylenes Using an Alkene as Both a Directing Group and a Reaction Moiety
    Hideaki Takano, Takeharu Ito, Kyalo Stephen Kanyiva, and Takanori Shibata Chem. Eur. J., 2018, 24, 15173-15177
    ★Selected as cover picture★
  45. Ir‐Catalyzed Enantioselective Intra‐ and Intermolecular Formal C-H Conjugate Addition to β‐Substituted α,β‐Unsaturated Esters
    Takanori Shibata, Hisaki Kurita, Sahoko Onoda, Kyalo Stephen Kanyiva Asian. J. Org. Chem., 2018, 7, 1411-1418
  46. α‐Amino Acid Sulfonamides as Versatile Sulfonylation Reagents: Silver‐Catalyzed Synthesis of Coumarins and Oxindoles by Radical Cyclization
    Kyalo Stephen Kanyiva Daisuke Hamada Sohei Makino Hideaki Takano Takanori Shibata Eur. J. Org. Chem., 2018, 5905-5909
    Selected as VIP (very important pater)
    Selected for Front cover
  47. 8‐exo‐dig‐Selective Cycloisomerization for the Synthesis of Dibenzo[b,e][1,4]diazocines Using Cationic AuI Catalysts
    Mamoru Ito, Daisuke Inoue, Asahi Takaki, Kyalo Stephen Kanyiva, Takanori Shibata Eur. J. Org. Chem., 2018, 4740-4747
  48. Ir-Catalyzed Synthesis of Substituted Tribenzosilepins by Dehydrogenative C-H/Si-H Coupling
    Takanori Shibata , Ninna Uno, Tomoya Sasaki, Hideaki Takano, Tatsuki Sato, and Kyalo Stephen Kanyiva J. Org. Chem., 2018, 83, 3426-3432
  49. Catalytic Dearomative Spirocyclization via Gold Carbene Species Derived from Ynamides: Efficient Synthesis of 2-Azaspiro[4.5]decan-3-ones
    Mamoru Ito, Ryosuke Kawasaki, Kyalo Stephen Kanyiva and Takanori Shibata Chem. Eur. J., 2018, 24, 3721-3724
  50. Metal-Free N-H/C-H Coupling for Efficient Synthesis of Chiral Dihydroquinoxalinones From Readily Available α-Amino Acids
    Kyalo Stephen Kanyiva, Masashi Horiuchi and Takanori Shibata Eur. J. Org. Chem., 2018, 1067-1070
  51. Silver-Catalyzed Efficient Synthesis of Oxindoles andPyrroloindolines via a-Aminoalkylation of N-Arylacrylamides withAmino Acid Derivatives
    Kyalo Stephen Kanyiva, Sohei Makino and Takanori Shibata Chem. Asian J., 2018, 13, 496-499
    ★Selected for Front cover★
    ★Highlighted in Chemistryviews★

    52. 2017

  52. Cationic Au(I)-Catalyzed Cycloisomerization of N-(2-Alkynylphenyl)indolines for the Construction of Indolobenzazepine Skeleton
    Mamoru Ito, Daisuke Inoue, Ryosuke Kawasaki, Kyalo Stephen Kanyiva and Takanori Shibata Heterocycles, 2017, 94, 2229-2246
  53. Enantioselective Synthesis of Sulfur-Containing Medium-RingHeterocycles with Axial Chiralities by Catalytic Intramolecular[2+2+2] Cycloaddition
    Akihito Mitake, Toru Fusamae, Kyalo Stephen Kanyiva, and Takanori Shibata Eur. J. Org. Chem., 2017, 7266-7270
  54. DFT Studies on the Mechanism of the Iridium-Catalyzed Formal [4 + 1] Cycloaddition of Biphenylene with Alkenes
    Hideaki Takano, Natsuhiko Sugimura, Kyalo Stephen Kanyiva, and Takanori Shibata ACS Omega, 2017, 2, 5228-5234
  55. Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes
    Takanori Shibata, Akihito Mitake, Yosuke Akiyama, and Kyalo Stephen Kanyiva Chem. Commun., 2017, 53, 9016-9019
  56. Thermally Stable Monosubstituted Thiophene 1-Oxide and 1-Imides Stabilized by a Bulky Rind Group at Their 3-Position: Synthesis, Structure, and Inversion Barriers on the Sulfur Atom
    Takashi Otani, Mayu Miyoshi, Takanori Shibata, Tsukasa Matsuo, Daisuke Hashizume, and Kohei Tamao Bull. Chem. Soc. Jpn. 2017, 90, 697-705
    ★Selected paperに選出されました★
  57. Intramolecular C-H Alkenylation of N-Alkynylindoles: Exo and Endo Selective Cyclization According to the Choice of Metal Catalyst
    Takanori Shibata, Takumi Baba, Hideaki Takano, and Kyalo Stephen Kanyiva Adv. Synth. Catal. 2017, 359, 1849-1853
    ★Selected as VIP (very important pater)★
  58. Facile Two-Step Synthesis of 1,10-Phenanthroline-Derived Polyaza[7]helicenes with High Fluorescence and CPL Efficiency
    Takashi Otani, Ami Tsuyuki, Taiki Iwachi, Satoshi Someya, Kotaro Tateno, Hidetoshi Kawai, Takao Saito, Kyalo Stephen Kanyiva, Takanori Shibata Angew. Chem. Int. Ed. 2017, 56, 3906-3910
    ★Highlighted in Synfacts 2017, 69.★
    ★Selected as SYNFACT of the month.★
    ★大学のプレスリリースで紹介されました★
  59. Catalytic Intramolecular [2+2+2] Cycloaddition of Peptide-Tethered Branched Triynes for the Synthesis of Cyclic Peptides
    Shuhei Obinata, Yu-ki Tahara, Kyalo Stephen Kanyiva, and Takanori Shibata Heterocycles, 2017, 95, 1121-1131
  60. Enantioselective Formal C-H Conjugate Addition of Acetanilides to beta-Substituted Acrylates by Chiral Iridium Catalysts
    Takanori Shibata, Masamichi Michino, Hisaki Kurita, Yu-ki Tahara, Kyalo Stephen Kanyiva Chem. Eur. J. 2017, 23, 88-91
  61. Point-to-Point Ultra-Remote Asymmetric Control with Flexible Linker
    Tsuneomi Kawasaki, Yasuyuki Ishikawa, Yoshihiro Minato, Takashi Otsuka, Shigeru Yonekubo, Itaru Sato, Takanori Shibata, Arimasa Matsumoto, Kenso Soai Chem. Eur. J. 2017, 23, 282-285

    62. 2016

  62. Raman study on pentacene:C60 bulk heterojunction films
    Yasuhiro Iwasawa, Tomoya Sasaki, Takanori Shibata, Yukio Furukawa, Vibrational Spectroscopy 2016, 84, 133-138.
  63. Construction of a Polycyclic Conjugated System Containing a Dibenzazepine Moiety by Cationic Au(I)-Catalyzed Cycloisomerization
    Mamoru Ito, Ryosuke Kawasaki, Kyalo Stephen Kanyiva, Takanori Shibata Eur. J. Org. Chem. 2016, 31, 5234-5237.
  64. Enantioselective synthesis of planar-chiral 1,11-dioxa[11]paracyclophane-derived phosphoramidites and their use as chiral ligands
    Madhurima Hazra, Kyalo Stephen Kanyiva, Takanori Shibata Tetrahedron: Asymmetry 2016, 20-21, 1081-1087.
  65. Pt-Catalyzed Enantioselective Cycloisomerization for the Synthesis of Planar-Chiral Ferrocene Derivatives
    Takanori Shibata, Ninna Uno, Tomoya Sasaki, and Kyalo Stephen Kanyiva J. Org. Chem. 2016, 81, 6266-6272.
  66. Enantioselective Synthesis of Planar-Chiral 1,n-Dioxa[n]paracyclophane-Based Phosphites and Their Application as Chiral Ligands
    Takanori Shibata, Miku Fukai, Ryosuke Sekine, Madhurima Hazra, Kyalo Stephen Kanyiva Synthesis 2016, 48, 2664-2670.
  67. Iridium-Catalyzed Formal [4 + 1] Cycloaddition of Biphenylenes with Alkenes Initiated by C?C Bond Cleavage for the Synthesis of 9,9-Disubstituted Fluorenes
    Hideaki Takano, Kyalo Stephen Kanyiva, and Takanori Shibata Org. Lett. 2016, 18, 1860-1863.
  68. Catalytic and Enantioselective Synthesis of Chiral Multisubstituted Tribenzothiepins by Intermolecular Cycloadditions
    Yu-ki Tahara, Riku Matsubara, Akihito Mitake, Tatsuki Sato, Kyalo Stephen Kanyiva, and Takanori Shibata Angew. Chem. Int. Ed. 2016, 55, 4552-4556.

    ★Highlighted in Synfacts 2016, 0488.★
  69. Enantioselective Synthesis of Aminoindan Carboxylic Acid Derivatives by the Catalytic Intramolecular [2+2+2] Cycloaddition of Amino Acid-Tethered Triynes
    Yu-ki Tahara, Shuhei Obinata, Kyalo Stephen Kanyiva, Takanori Shibata, Attila Mandi, Tohru Taniguchi, Kenji Monde Eur. J. Org. Chem. 2016, 2016, 1405-1413.
  70. Strategies for the Total Synthesis of Clavicipitic Acid
    Mamoru Ito; Yu-ki Tahara; Takanori Shibata Chem. Eur. J. 2016, 22, 5468-5477.
  71. Multi-Substituted Dibenzophosphole Oxide Synthesis by the Catalytic [2+2+2] Cycloaddition of Phosphoryl-Benzene-Tethered Diynes with Various Alkynes
    Yu-ki Tahara, Tatsuki Sato, Riku Matsubara, Kyalo Stephen Kanyiva, Takanori Shibata Heterocycles, 2016, 93, 685-705
  72. 炭素－水素結合活性化を起点とする触媒的不斉合成
    柴田　高範　ファインケミカル、2016年、45巻、P6-14

    73. 2015

  73. Enantioselective sp3 C-H alkylation of γ-butyrolactam by a chiral Ir(I) catalyst for the synthesis of 4-substituted γ-amino acids
    Tahara, Y.; Michino, M.; Ito, M.; Kanyiva, K. S.; Shibata, T. Chem. Commun., 2015, 51, 16660-16663.
  74. Total Synthesis of cis-Clavicipitic Acid from Asparagine via Ir-Catalyzed C-H bond Activation as a Key Step
    Tahara, Y.; Ito, M.; Kanyiva, K. S.; Shibata, T. Chem. Eur. J., 2015, 21, 11340-11343.
    Selected as Hot Topics of C-H activation in Wiley Journals
  75. Ir-Catalyzed Intramolecular Enantioselective C-H Alkylation at the C2 Position of N-Alkenylindoles
    Shibata, T.; Ryu, N.; Takano, H. Adv. Synth. Catal., 2015, 357, 1131-1135.
    Selected as VIP.

    ★Selected as Inside Cover Picture!★

  76. Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation
    Shibata, T.; Shizuno, T.; Sasaki, T. Chem. Commun., 2015, 51, 7802-7804.

    ★Selected as Inside Back Cover Picture!★

  77. Cationic Iridium-Catalyzed C-H Alkylation of 2-Substituted Pyridine N-Oxides with Acrylates
    Shibata, T.; Takano, H. Org. Chem. Front., 2015, 2, 383-387.
    .

  78. Asymmetric synthesis of multi-substituted triptycenes via enantioselective alkynylation of 1, 5-dibromoanthracene-9, 10-dione
    Shibata, T.; Kamimura, Y. Tetrahedron: Asymmetry, 2015, 26, 41-45.

  79. [2+2+2] Cycloaddition of Sulfanylbenzene-Tethered Diynes with Alkynes for the Synthesis of Multi-Substituted Dibenzothiophene Derivatives
    Tahara, Y.; Matsubara, R.; Shibata, T. Heterocycles 2015, 90, 1094-1110 (special edition in honor of Prof. Isao Kuwajima).


    80. 2014

  80. Catalytic [2 + 2 + 2] Cycloaddition of Benzothiophene Dioxides with α,ω-Diynes for the Synthesis of Condensed Polycyclic Compounds
    Tahara, Y.; Gake, M.; Matsubara, R.; Shibata, T. Org. Lett., 2014, 16, 5980-5983.


  81. Synthesis of macrocyclic heteroarylenes by consecutive inter- and intramolecular cycloadditions of thiophenylene-tethered triynes
    Shibata, T.; Fujimoto, M.; Otani. T. Tetrahedron 2014, 70, 8453-8461.


    ★Highlighted in Synfacts 2014, 1043.★
  82. One-Pot Cross-Coupling of Diborylmethane for the Synthesis of Dithienylmethane Derivatives
    Endo, K.; Ishioka, T.; Shibata, T. Synlett 2014, 25, 2184-2188.


    ★Highlighted in Synfacts 2014, 1265.★
  83. Synthesis of Multicyclic Heterocycles Initiated by C-H Bond Activation Along with "Rollover" Using a Rh(III) Catalyst
    Shibata, T.; Takayasu, S. Heteroatom Chem. 2014, 25, 379-388. (special edition in honor of Prof. Renji Okazaki).


  84. Highly Chemo-, Enantio-, and Regioselective Synthesis of α,α-Disubstituted Furanones by Cu-Catalyzed Conjugate Addition
    Endo, K.; Yakeishi, S.; Takayama, R.; Shibata, T. Eur. J. Chem. 2014, 20, 8893-8897.


    ★Highlighted in Synfacts 2014, 1043.★
  85. Directed C-H Alkenylation of Quinoline N-Oxides at the C-8 Position Using a Cationic Rhodium(I) Catalyst
    Shibata, T.; Matsuo, Y. Adv. Synth. & Catal. 2014, 356, 1516-1520.


  86. Iridium-Catalyzed Enantioselective C-H Alkylation of Ferrocenes with Alkenes Using Chiral Diene Ligands
    Shibata, T.; Shizuno, T. Angew. Chem. Int. Ed. 2014, 53, 5410-5413.


    ★Highlighted in Synfacts 2014, 831.★
  87. Ir(III)-Catalyzed C7-Position-Selective Oxidative C-H Alkenylation of Indolines with Alkenes in Air
    Pan, S; Wakaki, T; Ryu, N; Shibata, T. Chem. Asian J. 2014, 9, 1257-1260.


  88. Iridium(I)-Catalyzed Direct C-H Bond Alkylation of the C-7 Position of Indolines with Alkenes
    Pan, S.; Ryu, N.; Shibata, T. Adv. Synth. Catal. 2014, 356, 929-933.

    ★Selected as Cover Picture!★
  89. Enantioselective Synthesis of Planar-Chiral Phosphines with 1,N-Dioxa[N]paracyclophane Scaffold and Their Application as Chiral Ligands
    Kanda, K.; Ohshima, S.; Shizuno, T.; Hamanaka, R.; Fukai, M.; Shibata, T. Heterocycles 2014, 88, 1355-1370. (Special edition in honor of Prof. Victor Snieckus).


    90. 2013

  90. Cationic Iridium-Catalyzed Synthesis Initiated by the Cleavage of C-H, N-H, and C-O Bonds
    Shibata, T.; Tsuchikama, K.; Pan, S. J. Synth. Org. Chem. Jpn. (English Edition) 2013, 71, 1182-1194. (Account)


  91. BINAM-mono-PHOS as New Entry for Multinuclear Cu-Catalysts in Asymmetric Conjugate Addition of Organozinc Reagents
    Endo, K.; Takayama, R.; Shibata, T. Synlett 2013, 24, 1155-1159.


    ★Highlighted in Synfacts 2013, 959.★
  92. Functionalized BINOL-mono-PHOS for Multinuclear Cu-Catalysts in Asymmetric Conjugate Addition of Organozinc Reagents
    Endo, K.; Yakeishi, S.; Hamada, D.; Shibata, T. Chem. Lett. 2013, 42, 547-549.


  93. Ir(I)-Catalyzed Synthesis of N-Substituted Pyridones from 2-Alkoxypyridines via CO Bond Cleavage
    Pan, S.; Ryu, N.; Shibata, T. Org. Lett. 2013, 15, 1902-1905.


  94. Recent Advances in Iridium-Catalyzed Alkylation of C-H and N-H Bonds
    Pan, S.; Shibata, T. ACS Catalysis 2013, 3, 704-712.


  95. Effect of Multinuclear Cu/Al-Complexes in Highly Asymmetric Conjugate Addition of Trimethylaluminum to Acyclic Enones
    Endo, K.; Hamada, D.; Yakeishi, S.; Shibata, T. Angew. Chem. Int. Ed. 2013, 52, 606-610.


    ★Highlighted in Synfacts 2013, 299.★

    96. 2012

  96. Rh(Ⅲ)-catalyzed directed C-H bond amidation of ferrocenes with isocyanates
    Takebayashi, S.; Shizuno, T.; Otani, T.; Shibata, T. Beilstein J. Org. Chem. 2012, 8, 1844-1848.


  97. Ir(I)-Catalyzed C-H Bond Alkylation of C2-Position of Indole with Alkenes: Selective Synthesis of Linear or Branched 2-Alkylindoles
    Pan, S.; Ryu, N.; Shibata, T. J. Am. Chem. Soc. 2012, 134, 17474-17477.


  98. Facile Synthesis of Cyclic Polyphenylenes by Consecutive Inter- and Intramolecular Cycloadditions of Ortho, Meta, and Para-Phenylene-Tethered Triynes
    Shibata, T.; Fujimoto, M.; Hirashima, H.; Chiba, T.; Endo, K. Synthesis 2012, 44, 3269-3284.


    ★Selected as Feature Article!!★
  99. Rh(Ⅲ)-Catalyzed C-H Bond Activation along with “Rollover” for the Synthesis of 4-Azafluorenes
    Shibata, T.; Takayasu, S.; Yuzawa, S.; Otani, T. Org. Lett. 2012, 14, 5106-5109.


  100. Cationic iridium-catalyzed enantioselective activation of secondary sp3 C-H bond adjacent to nitrogen atom
    1 Pan, S.; Matsuo, Y.; Endo, K.; Shibata, T. Tetrahedron 2012, 68, 9009-9015.


  101. One-Pot Synthesis of Symmetrical and Unsymmetrical Diarylmethanes via Diborylmethane
    Endo, K.; Ishioka, T.; Ohkubo, T.; Shibata, T. J. Org. Chem. 2012, 77, 7223-7231.


    ★Selected as Featured Article!!★
  102. Reversal enantioselectivity induced by achiral alcohols in asymmetric autocatalysis in the presence of a chiral diol as a chiral initiator
    Shibata, T.; Tarumi, H.; Kawasaki, T.; Soai, K. Tetrahedron: Asymmetry 2012, 23, 1023-1027.


  103. [Ir(cod)2]BARF-Catalyzed C-H Bond Alkenylation and Alkylation of Ferrocenes
    Takebayashi, S.; Shibata, T. Organometallics 2012, 31, 4114-4117.

  104. Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature
    Endo, K.; Ohkubo, T.; Ishioka, T.; Shibata, T. J. Org. Chem. 2012, 77, 4826-4831.

  105. Multinuclear Cu-catalyzed Based on SPINOL-PHOS in Asymmetric Conjugate Addition of Organozinc Reagents
    Endo, K.; Hamada, D.; Yakeishi, S.; Ogawa, M; Shibata, T. Org. Lett. 2012, 14, 2342-2345.


    ★Highlighted in Synfacts 2012, 878.★
  106. Detour and Direct Induction of Methyl-Containing Chiral Centers via Catalytic C-H or C-C Bond Formation
    Endo, K.; Shibata, T. Synthesis 2012, 44, 1427-1452. (Review)


  107. Ru-catalyzed β-selective and enantioselective addition of amines to styrenes initiated by direct arene-exchange
    Otsuka, M.; Yokoyama, H.; Endo, K.; Shibata, T. Org. Biomol. Chem. 2012, 10, 3815-3818.


    ★Highlighted in Synfacts 2012, 881.★
  108. Enantioselective synthesis of tripodal cyclophanes and pyridinophanes by intramolecular [2+2+2] cycloaddition
    Shibata, T.; Miyoshi, M.; Uchiyama, T.; Endo, K.; Miura, N.; Monde, K. Tetrahedron 2012, 68, 2679-2686.

    ★Highlighted in Synfacts 2012, 494.★
  109. Ir(I)-Catalyzed Intermolecular Regio- and Enantioselective Hydroamination of Alkenes with Heteroaromatic Amines
    Pan, S.; Endo, K.; Shibata, T. Org. Lett. 2012, 14, 780-783.

  110. Asymmetric ortho-lithiation of 1,n-dioxa[n]paracyclophane derivatives for the generation of planar chirality
    Kanda, K.; Hamanaka, R.; Endo, K.; Shibata, T. Tetrahedron 2012, 68, 1407-1416.

  111. Highly enantioselective synthesis of silahelicenes using Ir-catalyzed [2+2+2] cycloaddition
    Shibata, T.; Uchiyama, T.; Yoshinami, Y.; Takayasu, S.; Tsuchikama, K.; Endo, K. Chem. Commun. 2012, 48, 1311-1313.

    112. 2011

  112. Stereoselective Synthesis of Allylsilanes Bearing Tetrasubstituted Olefin via 2,2-Diborylethylsilane
    Endo, K.; Sakamoto, A; Ohkubo, T; Shibata, T. Chem. Lett. 2011, 40, 1440-1442.

  113. Cationic Ir(I)-Catalyzed sp3 C-H Bond Alkenylation of Ureas with Alkynes for the Synthesis of 2,3-Disubstituted Indoles
    Shibata, T.; Hirashima, H.; Kasagawa, M.; Tsuchikama, K.; Endo, K. Synlett 2011, 2171-2176.

  114. Ir(I)-Catalyzes Enantioselective Secondary sp3 C-H Bond Activation of 2-(Alkylamino)pyridines with Alkenes
    Pan, S.; Endo, K.; Shibata, T. Org. Lett. 2011, 13, 4692-4695.

    ★Highlighted in Synfacts 2011, 1340.★
  115. Ir(III)-Catalyzed Room-Temperature Synthesis of Multisubstituted Benzofurans Initiated by C-H Activation of α-Aryloxy Ketones
    Shibata, T.; Hashimoto, Y-k.; Otsuka, M.; Tsuchikama, K.; Endo,K. Synlett 2011, 2075-2079.

  116. Regioselective Addition of Various Heteronucleophiles to (Styrene)Cr(CO)3 Complexes
    Otsuka, M.; Endo, K.; Shibata, T. Organometallics 2011, 30, 3683-3685.

  117. Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of Benzylboronates
    Endo, K.; Ohkubo, T.; Shibata, T. Org. Lett. 2011, 13, 3368-3371.

    ★Highlighted in Synfacts 2011, 1000.★
  118. Chiral Rh and Ir Catalyzed-Intramolecular Cycloaddition of Hexaynes for the Construction of New Chiral Skeletons
    Shibata, T.; Chiba, T.; Hirashima, H.; Ueno, Y.; Endo, K. Heteroatom Chem. 2011, 22, 363-370. (Dedicated to Prof. K-y. Akiba on the occasion of his 75th birthday.)

  119. Multinuclear Pd/Zn-complex Catalyzed Asymmetric Alkylative Ring Opening Reaction of Oxabicyclic Alkenes
    Endo, K.; Tanaka, K.; Ogawa, M.; Shibata, T. Org. Lett. 2011, 13, 868-871.

    ★Highlighted in Synfacts 2011, 644.★
  120. Enantioselective construction of new chiral cyclic scaffolds using [2 + 2 + 2] cycloaddition
    Shibata, T.; Uchiyama, T.; Hirashima, H.; Endo, K. Pure Appl. Chem. 2011, 83, 597-605.

    121. 2010

  121. Facile Catalytic SNAr Reaction of Nonactivated Fluoroarenes with Amines Using η6-Benzene Ru(II) Complex
    Otsuka, M.; Yokoyama, H.; Endo, K.; Shibata, T. Synlett 2010, 2601-2606.

  122. Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature
    Endo, K.; Ohkubo, T.; Hirokami, M.; Shibata, T. J. Am. Chem. Soc. 2010, 132, 11033-11035.


  123. Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates
    Endo, K.; Hirokami, M.; Shibata, T. J. Org. Chem. 2010, 75, 3469-3472.

    ★Highlighted in Synfacts 2010, 852.★
  124. Enantioselective Intramolecular [2+2+2] Cycloaddition of Dienynes for the Construction of Adjacent Three Chiral Centers
    Shibata, T.; Otomo, M.; Endo, K. Synlett 2010, 8, 1235-1238.

  125. Enantioselective Synthesis of Planar-Chiral 1,n-Dioxa[n]paracyclophanes via Catalytic Asymmetric Ortho-Lithiation
    Kanda, K.; Endo, K.; Shibata, T. Org. Lett. 2010, 12, 1980-1983.

    ★Highlighted in Synfacts 2010, 777.★
  126. Multinuclear Catalyst for Copper-Catalyzed Asymmetric Conjugate Addition of Organozinc Reagents
    Endo, K.; Ogawa, M.; Shibata, T. Angew. Chem. Int. Ed. 2010, 49, 2410-2413.

    ★Highlighted in Synfacts 2010, 679.★
  127. Sequential Catalytic Reactions for the Synthesis of Benzofulvenes Using an Iridium Complex with Dual Function
    Tsuchikama, K.; Kasagawa, M.; Endo, K.; Shibata, T. Synlett 2010, 97-100.

    ★Highlighted in Synfacts 2010, 294.★
  128. Catalytic SNAr reaction of non-activated fluoroarenes with amines via Ru η6-arene complexes
    Otsuka, M.; Endo, K.; Shibata, T. Chem. Commun. 2010, 46, 336-338.


    ★本論文は化学ポータルサイトCHEM-STATIONの化学者のつぶやきで取り上げられました★

    129. 2009

  129. Iridium-Catalyzed Selective Synthesis of 4-Substituted Benzofurans and Indoles via Directed Cyclodehydration
    Tsuchikama, K.; Hashimoto, Y.; Endo, K.; Shibata, T. Adv. Synth. Catal. 2009, 351, 2850-2854.


    ★Highlighted in Synfacts 2010, 153.★
  130. Catalytic Enantioselective Synthesis of Chiral Tetraphenylenes: Consecutive Inter- and Intramolecular Cycloadditions of Two Triynes
    Shibata, T.; Chiba, T.; Hirashima, H.; Ueno, Y.; Endo, K. Angew. Chem. Int. Ed . 2009, 48, 8066-8069.

    ★Selected as VIP (Very Important Paper)!! ★
  131. Enantioselective Synthesis of Chiral Tripodal Cage Compounds by [2 + 2 + 2] Cycloaddition of Branched Triynes
    Shibata, T.; Uchiyama, T.; Endo, K. Org. Lett. 2009, 11, 3906-3908.


    ★Highlighted in Synfacts 2009, 1364.★
  132. Synthesis of 1,1-Organodiboronates via Rh(I)Cl-Catalyzed Sequential Regioselective Hydroboration of 1-Alkynes
    Endo, K.; Hirokami, M.; Shibata, T. Synlett 2009, 1331-1335.


  133. Cationic Ir(I)-Catalyzed sp3 C-H Bond Alkenylation of Amides with Alkynes
    Tsuchikama, K.; Kasagawa, M.; Endo, K.; Shibata, T. Org. Lett. 2009, 11, 1821-1823.


    ★Highlighted in Synfacts 2009, 782.★
  134. The first asymmetric Sonogashira coupling for the enantioselective generation of planar chirality in paracyclophanes
    Kanda, K.; Koike, T.; Endo, K.; Shibata, T. Chem. Commun. 2009, 1870-1872.


    135. 2008

  135. DMAP-Accelerated Rhodium(I) Chloride Catalyzed Hydroboration of Vinyl arenes
    Endo, K.; Hirokami, M.; Takeuchi, K.; Shibata, T. Synlett 2008, 30, 3231-3233.


  136. Cationic iridium-BINAP complex-catalyzed addition of aryl ketones to alkynes and alkenes via directed C-H bond cleavage
    Tsuchikama, K.; Kasagawa, M.; Hashimoto, Y.; Endo, K.; Shibata, T. J. Organomet. Chem. 2008, 693, 3939-3942.


  137. Highly diastereo- and enantioselective construction of both central and axial chiralities by Rh-catalyzed [2+2+2] cycloaddition
    Shibata, T.; Otomo, M.; Tahara, Y.; Endo, K. Org. Biomol. Chem. 2008, 6, 4296-4298.


  138. Counteranion-Accelerated Rh(Ⅰ)OAc-Catalyzed Regioselective Hydroboration of Vinylarenes
    Endo, K.; Hirokami, M.; Shibata,, T. Organometallics 2008, 27, 5390-5393.


  139. Rhodium-catalyzed Intramolecular Cycloaddition of Cyclopropene-ynes Triggered by Carbon-Carbon bond Cleavage
    Shibata, T.; Maekawa, S; Tamura, K. Heterocycles 2008, 76, (Dr. Ryoji Noyori Special Issue), 1261-1270.

  140. 触媒的不斉付加環化反応によるキラル環状化合物の合成
    柴田　高範，土釜　恭直 ファインケミカル (2008年5月号), 55-67. (総合論文)

    Catalytic synthesis of chiral cyclic compounds by enantioselective cycloaddition.
    Shibata, T.; Tsuchikama, K. Fainkemikaru 2008, 37, 55-67. (Account)
  141. Recent advances in enantioselective [2+2+2] cycloaddition
    Shibata, T.; Tsuchikama, K. Org. Biomol. Chem. 2008, 1317-1323. (Account)


    ★Selected as Hot Articles★
    ★This article is Top 10 most downloaded OBC articles in April 2008.★
  142. Iridium-Catalyzed Enantioselective Formal [4+2] Cycloaddition of Biphenylene and Alkynes for the Construction of Axial Chirality
    Shibata, T.; Nishizawa, G.; Endo, K. Synlett 2008, 765-768.


  143. Enantioselective Syntheses of Various Chiral Multicyclic Compounds with Quaternary Carbon Stereocenters by Catalytic Intramolecular Cycloaddition
    Shibata, T.; Tahara, Y.; Tamura, K.; Endo, K. J. Am. Chem. Soc. 2008, 130, 3451-3457.


  144. Carbonylative and Hydrosilylative Carbocyclization of 1,5-Diynes for the Synthesis of Cyclic Dienones
    Shibata, T.; Nakagawa, N.; Ueno, Y.; Endo, K. Organometallics 2008, 27, 1342-1344.


  145. Rh-catalyzed intermolecular and enantioselective [4+2] cycloaddition of 1,3-dienes with dimethyl acetylenedicarboxylate
    Shibata, T.; Fujiwara, D.; Endo, K. Org. Biomol. Chem. 2008, 6, 464-467.


  146. Iridium-catalyzed consecutive and enantioselective [2+2+2] cycloaddition of tetraynes and hexaynes for the construction of axially chiral biaryl system
    Shibata, T.; Yoshida, S.; Arai, Y.; Otsuka, M.; Endo, K. Tetrahedron 2008, 64, 821-830.


    147. 2007

    Rhodium-catalyzed enantioselective [2+2+2] cycloaddition of diynes with unfunctionalized alkene
    Shibata, T.; Kawachi, A.; Ogawa, M.; Kuwata, Y.; Tsuchikama, K.; Endo, K. Tetrahedron 2007, 63, 12853-12859.


  147. Chiral secondary alcohol-induced asymmetric autocatalysis: correlation between the absolute configuration of the chiral initiators and the product chiral ortho-diarylbenzene derivatives
    Shibata, T.; Iwahashi, K.; Kawasaki, T.; Soai, K. Tetrahedron: Asymmetry 2007, 18, 1759-1762.


  148. Enantioselective [2+2+2] Cycloaddition of Endiynes for the Synthesis of Chiral Cyclohexa-1,3-dienes
    Shibata, T.; Kurokawa, H.; Kanda, K. J. Org. Chem. 2007, 72, 6521-6525.


  149. Rh-Catalyzed Cyclization of Diynes and Enynes Initiated by Carbonyl-Directed Activation of Aromatic and Vinylic C-H Bonds
    Tsuchikama, K.; Kuwata, Y.; Tahara, Y.; Yoshinami, Y.; Shibata, T. Org. Lett. 2007, 9, 3097-3099.


    ★Highlighted in Synfacts 2007, 1071.★
  150. Rhodium Complex-Catalyzed [2+2+2] Cycloaddition of Diynes and Carbonyl Compounds
    Tsuchikama, K.; Yoshinami, Y.; Shibata, T. Synlett 2007, 1395-1398.


    151. 2006

    Iridium-Catalyzed Enantioselective [2+2+2] Cycloaddition of Diynes and Monoalkynes for the Generation of Axial Chiralities
    Shibata, T.; Arai, Y.; Takami, K.; Tsuchikama, K.; Fujimoto, T.; Takebayashi, S.; Takagi, K. Adv. Synth. Catal. 2006, 348, 2475-2483.


  151. Recent Advances in the Catalytic Pauson-Khand-Type Reaction
    Shibata, T. Adv. Synth. Catal. 2006, 348, 2328-2336. (Review)


  152. Highly Enantioselective Construction of a chiral Spirocyclic Structure by the [2 + 2 + 2] Cycloaddition of Diynes and exo-Methylene Cyclic Compounds
    Tsuchikama, K.; Kuwata, Y.; Shibata, T. J. Am. Chem. Soc. 2006, 128, 13686-13687.　


    ★Highlighted in Synfacts 2007, 183.★
  153. 「イリジウム、ロジウム錯体を用いる触媒的付加環化反応の開発」
    柴田　高範, 有機合成化学協会誌, 2006, 64, 913-922. (総合論文)　

    Iridium and Rhodium Complex-Catalyzed Cycloadditions
    Shibata, T. J. Synth. Org. Chem., Jpn. 2006, 64, 913-922. (Account)
  154. Enantioselective Intramolecular [2 + 2 + 2] Cycloaddition of 1,4-Diene-ynes: A New Approach to the Construction of Quaternary Carbon Stereocenters
    Shibata, T.; Tahara, Y. J. Am. Chem. Soc. 2006, 128, 11766-11767.　


    ★Highlighted in Synfacts 2007, 69.★
    ★Selected as SYNFACT of the month.★
  155. Cationic Au(I)- and Pt(II)- catalyzed silylation of alcohols using Allylsilane
    Shibata, T.; Kanda, K.; Ueno, Y.; Fujiwara, R. Bull. Chem. Soc. Jpn. 2006, 79, 1146-1147.


  156. Enantioselective intramolecular [2+2+2] cycloaddition of triynes for the synthesis of atropisomeric chiral ortho-diarylbenzene derivatives
    Shibata, T.; Tsuchikama, K.; Otsuka, M. Tetrahedron: Asymmetry 2006, 17, 614-619.


    ★This article is "Top-50 most cited articles" as published in Tetrahedron: Asymmetry 2006-2009.★
  157. Rh-Catalyzed Enantioselective [2 + 2] Cycloaddition of Alkynyl Esters and Norbornene Derivatives
    Shibata, T.; Takami, K.; Kawachi, A. Org. Lett. 2006, 8, 1343-1345.


  158. Cationic Au(I)-Catalyzed Cycloisomerization of Aromatic Enynes for the Synthesis of Substituted Naphthalenes
    Shibata, T.; Ueno, Y.; Kanda, K. Synlett 2006, 411-414.


  159. Ir-catalyzed almost perfect enantioselective synthesis of helical polyaryls based on an axially-chiral sequence
    Shibata, T.; Tsuchikama, K. Chem. Commun. 2005, 48, 6017-6019.


    ★Highlighted in Synfacts 2006, 230.★

    160. 2005

  160. Enantioselective Construction of Quaternary Carbon Centers by Catalytic [2+2+2] Cycloaddition of 1,6-Enynes and Alkynes
    Shibata, T.; Arai, Y.; Tahara, Y. Org. Lett. 2005, 7, 4955-4957.
  161. Iridium-catalyzed enantioselective Pauson-Khand-type reaction of 1,6-enynes
    Shibata, T.; Toshida, N.; Yamasaki, M.; Maekawa, S.; Takagi, K. Tetrahedron 2005, 61, 9974-9979.


  162. Iridium-catalyzed enantioselective cycloisomerization of nitrogen-bridged 1,6-enynes to 3-azabicylo[4.1.0]heptenes
    Shibata, T.; Kobayashi, Y.; Maekawa, S.; Toshida, N.; Takagi, K. Tetrahedron 2005, 61, 9018-9024.


  163. Thermal and Au(I)-Catalyzed Intramolecular [4+2] Cycloaddition of Aryl-Substituted 1,6-Diynes for the Synthesis of Biaryl Compounds
    Shibata, T.; Fujiwara, R.; Takano, D. Synlett 2005, 2062-2066.


  164. Cationic Platinum-Catalyzed Etherification by Intra- and Intermolecular Dehydration of Alcohols
    Shibata, T.; Fujiwara, R.; Ueno, Y. Synlett 2005, 152-154.


  165. The Reaction of Butatrienolates with Aldehydes for the Syntheses of α-Vinylidene Acylsilanes
    Shibata, T.; Takami, K.; Arai, Y.; Tsuchikama, K.; Maekawa, S. Bull. Chem. Soc. Jpn. 2004, 77, 1937-1938.


  166. Iridium Complex-Catalyzed Highly Enantio- and Diastereoselective [2+2+2] Cycloaddition for the Synthesis of Axially Chiral Teraryl Compounds
    Shibata, T.; Fujimoto, T.; Yokota, K.; Takagi, K. J. Am. Chem. Soc. 2004, 126, 8382-8383.


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